Electrochemical Halogenation of Organic Compounds

被引：40
|
作者：
Lyalin, B. V. [1 ]
Petrosyan, V. A. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow, Russia
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2013年 / 49卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
halogenation; organic compounds; electrochemical synthesis; PHASE-TRANSFER CATALYST; 2 IMMISCIBLE LIQUIDS; ONE-POT SYNTHESIS; ANODIC CHLORINATION; AROMATIC-COMPOUNDS; ALPHA-BROMINATION; 2-PHASE ELECTROLYSIS; GENERATED IODINE(I); THIOPHENE SERIES; N-HALOGENATION;
D O I：
10.1134/S1023193513060098
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Data on the electrochemical chlorination, bromination, and iodination of organic compounds from various classes were summarized and systematized. The influence of the nature of the halogen and organic substrate on these processes was discussed. Data on the effects of the solvent, anode material, current density, and temperature on electrohalogenation were analyzed. The main tendencies of these reactions and their peculiarities as reactions of hydrogen substitution in the substrate were considered.
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页码：497 / 529
页数：33
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