Heteropolyacid-impregnated PVDF as a solid polymer electrolyte for dye-sensitized solar cells

被引：60
|
作者：
Anandan, S.
Pitchumani, S.
Muthuraaman, B.
Maruthamuthu, P.
机构：
[1] Cent Electrochem Res Inst, Madras Unit, Madras 600113, Tamil Nadu, India
[2] Univ Madras, Dept Energy, Madras 600025, Tamil Nadu, India
来源：
SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2006年 / 90卷 / 12期
关键词：
dye-sensitized solar cells; heteropolyacid; polymer electrolyte; solar energy conversion;
D O I：
10.1016/j.solmat.2005.09.005
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Heteropolyacid (HPA)-impregnated polyvinylidene fluoride (PVDF) with iodine/iodide was prepared as a new polymer electrolyte for bio-mimicking natural photosynthesis. With this new polymer electrolyte, dye-sensitized solar cell was fabricated using N3 dye-adsorbed over TiO2 nanoparticles (photoanode) and conducting carbon cement coated on conducting glass (photocathode). The fabricated cell generates high open circuit voltage (V-OC 426mV) and short circuit current (I-SC 3.90mA) upon illumination with visible light. It is also demonstrated that the polymer electrolytes prevent the back-electron transfer reactions taking place in dye-sensitized hetero-junctions and are highly promising for solar energy conversion to electricity. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：1715 / 1720
页数：6
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