Reactivity comparison of high-valent iron(IV)-oxo complexes bearing N-tetramethylated cyclam ligands with different ring size

被引：56
作者：
Hong, Seungwoo [1 ]
So, Hee [1 ]
Yoon, Heejung [1 ,2 ,3 ]
Cho, Kyung-Bin [1 ]
Lee, Yong-Min [1 ]
Fukuzumi, Shunichi [1 ,2 ,3 ]
Nam, Wonwoo [1 ]
机构：
[1] Ewha Womans Univ, Dept Chem & Nano Sci, Dept Bioinspired Sci, Seoul 120750, South Korea
[2] Osaka Univ, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan
[3] ALCA JST, Suita, Osaka 5650871, Japan
来源：
DALTON TRANSACTIONS | 2013年 / 42卷 / 22期
关键词：
NONHEME (FEO)-O-IV COMPLEXES; ELECTRON-TRANSFER PROPERTIES; C-H BONDS; SPECTROSCOPIC CHARACTERIZATION; OXOIRON(IV) COMPLEXES; OXYGENATION REACTIONS; OXO COMPLEXES; IRON ENZYMES; GENERATION; CHEMISTRY;
D O I：
10.1039/c3dt50750e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The ring size effect of macrocyclic TMC ligands in nonheme iron(IV)-oxo complexes has been examined in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; an iron(IV)-oxo complex bearing a smaller TMC ligand is more reactive in both HAT and OAT reactions, resulting from its high Fe-IV/III redox potential.
引用
收藏
页码：7842 / 7845
页数：4
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