Syntheses, Crystal Structures, and Fluorescent Properties of Two Binuclear Hg(II) Complexes Based on 2-((Benzoimidazolyl)methyl)-1H-tetrazole

被引：7
|
作者：
Ding, Yanan [1 ]
Zhou, Xiaoli [2 ]
Jin, Guanghua [1 ]
Zhao, Dong [1 ]
Meng, Xiangru [1 ]
机构：
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
[2] Zhongzhou Univ, Expt Adm Ctr, Zhengzhou, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 03期
关键词：
complex; crystal structure; fluorescent property; synthesis; LUMINESCENT PROPERTIES; METAL-COMPLEXES; COORDINATION; TETRAZOLE; POLYMERS; ZINC(II); LIGANDS;
D O I：
10.1080/15533174.2011.611848
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new complexes formulated as [HgBr(bimt)(mu-Br)(2)HgBr(bimt)]center dot H2O (1), and [HgI(bimt)(mu-I)(2)HgI(bimt)] (2) (bimt = 2-((benzoimidazolyl)methyl)-1H-tetrazole) have been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Both complexes exhibit binuclear structure. In the solid state, there are hydrogen bonds and p-p interactions in both complexes, and there are still I center dot center dot center dot I interactions in 2. Their fluorescent properties also have been determined.
引用
收藏
页码：438 / 443
页数：6
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