Barrier and mechanical properties of biodegradable poly(ε-caprolactone)/cellophane multilayer film

被引：14
作者：
Shi, Cancan [1 ]
Zhang, Shuhong [1 ]
Li, Mengting [1 ]
Sun, Wenxiu [1 ]
Fan, Guisheng [1 ]
Jin, Ye [1 ]
Yang, Jinjun [2 ]
Dong, Tungalag [1 ]
机构：
[1] Inner Mongolia Agr Univ, Coll Food Sci & Engn, Hohhot 010018, Inner Mongolia, Peoples R China
[2] Tianjin Univ Technol, Sch Environm Sci & Safety Engn, Tianjin 300384, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2013年 / 130卷 / 03期
基金：
中国国家自然科学基金;
关键词：
biodegradable; mechanical properties; packaging; films; coatings; MICROFIBRILLATED CELLULOSE; EPSILON-CAPROLACTONE; THERMAL-PROPERTIES; CHITOSAN; COMPOSITES; MORPHOLOGY; POLYMERS;
D O I：
10.1002/app.39354
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this study, cellophane (PT) multilayer films were prepared by coating with different thickness of poly(epsilon-caprolactone) (PCL) and chitosan (CH), and its effects on barrier and mechanical properties were evaluated. It was shown that the PCL/PT/PCL and PCL/CH/PT/CH/PCL multilayer films exhibit much better water vapor barrier than PT, and these films still keep the high oxygen barrier. And the barrier properties of multilayer film were improved with the increase of the thickness of coating materials. The Young's modulus and tensile strength of PT multilayer film were slightly decreased, and their elongations at break were increased by coating. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 1805-1811, 2013
引用
收藏
页码：1805 / 1811
页数：7
相关论文
共 35 条
  • [1] Preparation, characterisation and computational study of poly(ε-caprolactone) based nanocomposites
    Avella, M
    Bondioli, F
    Cannillo, V
    Errico, ME
    Ferrari, AM
    Focher, B
    Malinconico, M
    Manfredini, T
    Montorsi, M
    [J]. MATERIALS SCIENCE AND TECHNOLOGY, 2004, 20 (10) : 1340 - 1344
  • [2] Biodegradable poly(lactic acid)-based hybrid coating materials for food packaging films with gas barrier properties
    Bang, Gree
    Kim, Seong Woo
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2012, 18 (03) : 1063 - 1068
  • [3] Water sorption behavior and gas barrier properties of cellulose whiskers and microfibrils films
    Belbekhouche, Sabrina
    Bras, Julien
    Siqueira, Gilberto
    Chappey, Corinne
    Lebrun, Laurent
    Khelifi, Bertine
    Marais, Stephane
    Dufresne, Alain
    [J]. CARBOHYDRATE POLYMERS, 2011, 83 (04) : 1740 - 1748
  • [4] Nano-hybrids incorporation into poly(ε-caprolactone) for multifunctional applications: Mechanical and barrier properties
    Bugatti, Valeria
    Costantino, Umberto
    Gorrasi, Giuliana
    Nocchetti, Morena
    Tammaro, Loredana
    Vittoria, Vittoria
    [J]. EUROPEAN POLYMER JOURNAL, 2010, 46 (03) : 418 - 427
  • [5] Correlation between degree of crystallinity, morphology, glass temperature, mechanical properties and biodegradation of poly (3-hydroxyalkanoate) PHAs and their blends
    El-Hadi, A
    Schnabel, R
    Straube, E
    Müller, G
    Henning, S
    [J]. POLYMER TESTING, 2002, 21 (06) : 665 - 674
  • [6] Polymerization of ε-caprolactone by sodium hydride: From the synthesis of the polymer samples to their thermal, mechanical and barrier properties
    Gorrasi, Giuliana
    Pappalardo, Daniela
    Pellecchia, Claudio
    [J]. REACTIVE & FUNCTIONAL POLYMERS, 2012, 72 (10) : 752 - 756
  • [7] Chitosan-graft-poly(ε-caprolactone)s:: An optimized chemical approach leading to a controllable structure and enhanced properties
    Guan, Xipeng
    Quan, Daping
    Shuai, Xintao
    Liao, Kairong
    Mai, Kancheng
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (12) : 2556 - 2568
  • [8] Self-organization of functional gradient structure in the biodegradable chitosan/poly(vinyl alcohol) blend film
    Hexig, B
    Alata, H
    Inoue, Y
    [J]. JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2005, 43 (21) : 3069 - 3076
  • [9] Thermal properties and crystallization behaviour of blends of poly(ε-caprolactone) with chitin and chitosan
    Honma, T
    Senda, T
    Inoue, Y
    [J]. POLYMER INTERNATIONAL, 2003, 52 (12) : 1839 - 1846
  • [10] Green composites from sustainable cellulose nanofibrils: A review
    Khalil, H. P. S. Abdul
    Bhat, A. H.
    Yusra, A. F. Ireana
    [J]. CARBOHYDRATE POLYMERS, 2012, 87 (02) : 963 - 979
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