Two potential pyridine-borane oligomer and polymer building blocks.: Structural characterisation of [NC5H4•C5H4N•B10H12•NC5H4•C5H4N] and [Me2S•B10H12•NC4H4N•B10H12•SMe2] by conventional and synchrotron X-ray methods

被引：7

作者：

Londesborough, MGS

Price, C

Thornton-Pett, M

Clegg, W

Kennedy, JD ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[3] SERC, Daresbury Lab, CLRC, Warrington WA4 4AD, Cheshire, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 07期

关键词：

borane copolymers; amine copolymers; crystal structures; synchrotron; oligomers;

D O I：

10.1016/S1387-7003(99)00074-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two five-unit Linear compounds, [NC5H4. C5H4N . B10H12. NC5H4. C5H4N] and [Me2S . B10H12. NC4H4N . B10H12. SMe2], have been isolated from the reactions of [6,9-(SMe2)(2)-arachno-B10H12] with 4,4'-bipyridyl and pyrazine (1,4-diazabenzene), respectively, and are characterised by single-crystal X-ray diffraction analysis. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：298 / 300

页数：3

共 9 条

[1] Organometallic ''carbon chains'': They just keep getting longer! [J].