A Supramolecular Copper(II) Complex Bearing Salen-Type Bisoxime Ligand: Synthesis, Structural Characterization, and Thermal Property

被引：43

作者：

Zhao, Li ^{[1
]}

Wang, Li ^{[1
]}

Sun, Yin-Xia ^{[1
]}

Dong, Wen-Kui ^{[1
]}

Tang, Xiao-Lu ^{[1
]}

Gao, Xiong-Hou ^{[2
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

[2] PetroChina, Lanzhou Petrochem Res Ctr, Lanzhou, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 09期

关键词：

Cu-II complex; Salen-type ligand; supramolecular structure; synthesis; thermal property; CRYSTAL-STRUCTURE; COORDINATION POLYMER; NICKEL(II); CU(II); CO(II); PHENOLATE; ZINC(II); METAL; UNITS;

D O I：

10.1080/15533174.2012.684235

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A supramolecular Cu-II complex, [Cu(L)(H2O)] (H2L: 4,4',6,6'-tetrachloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol), has been synthesized and structurally characterized. X-ray crystallographic analysis shows that the complex is a centrosymmetric mononuclear Cu-II complex, and the Cu-II atom is penta-coordinated by two phenolic O atoms and two oxime N atoms from the deprotonated Salen-type ligand, and one oxygen atom from the coordinated water molecule. A self-assembling continual supramolecular structure is formed by intermolecular O3-H3 center dot center dot center dot O2 and O3-H3 center dot center dot center dot Cl1 hydrogen bonds.

引用

页码：1303 / 1308

页数：6

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