Synthesis and Characterization of New 1,2-Disubstituted Ferrocenyl Bismuthines

被引：7

作者：

Alcantara, Edith ^{[1
]}

Sharma, Pankaj ^{[1
]}

Perez, Diego ^{[1
]}

Cabrera, Armando ^{[1
]}

Vasquez, Jaime ^{[2
]}

Gutierrez, Rene ^{[3
]}

Hernandez, Simon ^{[1
]}

Toscano, Alfredo ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

[2] Univ Canada, Inst Farmacobiol, Oaxaca, Mexico

[3] Univ Autonoma Puebla, Fac Ciencias Quim, Puebla 72570, Mexico

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2012年 / 42卷 / 08期

关键词：

bismuthine; ferrocenyl; hypervalent; organobismuth; HYPERVALENT BOND FORMATION; COMPLEXES; STIBINES;

D O I：

10.1080/15533174.2012.680162

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bismuthine Ph(2)BiFc containing the pendant arm 2(Me2NCH2)-(1) on ferrocenyl ring was synthesized, and reaction of (1) with CH3I was carried out to obtain the monoammonium salt {[2-(Me3N+CH2)Fc]}BiPh2[I]-(2). Molecular structures of bismuthines (1) and (2) have been determined by X-ray crystallography. Compound (1) does not show hypervalent Bi-N interaction. New 1,2-disubstituted ferrocenyl bismuthines have been characterized by various physicochemical techniques.

引用

页码：1139 / 1142

页数：4

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