Recent Advances in Catalysts for Methane Combustion

被引:243
作者
Chen, Jinghuan [1 ,2 ]
Arandiyan, Hamidreza [1 ,3 ]
Gao, Xiang [2 ]
Li, Junhua [1 ]
机构
[1] Tsinghua Univ, Sch Environm, State Key Joint Lab Environm Simulat & Pollut Con, Beijing 100084, Peoples R China
[2] Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Zhejiang, Peoples R China
[3] Univ New S Wales, Sch Chem Engn, Particles & Catalysis Res Grp, Sydney, NSW 2052, Australia
基金
中国国家自然科学基金;
关键词
Heterogeneous catalysis; Catalytic combustion; Methane; Noble metal catalysts; Metal-oxide catalysts; ORDERED MACROPOROUS LA0.6SR0.4MNO3; DOPED HEXAALUMINATE CATALYSTS; LIGHT-DRIVEN DEGRADATION; RARE-EARTH-OXIDES; TOTAL OXIDATION; LOW-TEMPERATURE; CARBON-MONOXIDE; SUPPORTED PD; MIXED OXIDES; PALLADIUM CATALYSTS;
D O I
10.1007/s10563-015-9191-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This invited review highlights recent progress in the various classes of heterogeneous catalysts for methane combustion. These combustion catalysts provide a high-efficiency, clean energy source for natural gas vehicles and power plants. This review examines bimetallic systems, and a variety of oxides including single metal oxides, perovskites, spinels, and hexaaluminates. Noble metal mixed oxides exhibit superior catalytic activity due material-specific supports, additives, preparation methods, poisoning, regeneration and surface structure. Kinetic aspects, mechanisms, and the latest studies concerning density functional theory modelling are discussed in conjunction with particle oxidation/reduction mechanisms. The extensive background knowledge on the methane combustion reaction provided by this review provides guidance for researchers with interests ranging from the field of heterogeneous catalysis to the engineering of new high performance materials in environmental and chemical engineering.
引用
收藏
页码:140 / 171
页数:32
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