A Perspective on PEF Synthesis, Properties, and End-Life

被引：175

作者：

Loos, Katja ^{[1
]}

Zhang, Ruoyu ^{[2
]}

Pereira, Ines ^{[3
]}

Agostinho, Beatriz ^{[3
]}

Hu, Han ^{[2
]}

Maniar, Dina ^{[1
]}

Sbirrazzuoli, Nicolas ^{[4
]}

Silvestre, Armando J. D. ^{[3
]}

Guigo, Nathanael ^{[4
]}

Sousa, Andreia F. ^{[3
]}

机构：

[1] Univ Groningen, Zernike Inst Adv Mat, Macromol Chem & New Polymer Mat, Groningen, Netherlands

[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Biobased Polymer Mat Technol & Applicat Z, Ningbo, Peoples R China

[3] Univ Aveiro, Aveiro Inst Mat, CICECO, Dept Quim, Aveiro, Portugal

[4] Univ Cote dAzur, UMR 7272, Inst Chem, Nice, France

来源：

FRONTIERS IN CHEMISTRY | 2020年 / 8卷

关键词：

PEF; poly(ethylene 2; 5-furandicarboxylate); 2; 5-furandicarboxylic acid; green synthesis; biodegradation; nanomaterials; recycling; packaging applications; BIOBASED POLY(ETHYLENE 2,5-FURANDICARBOXYLATE); ENZYMATIC POLYMERIZATION; MECHANICAL-PROPERTIES; RENEWABLE RESOURCES; NONISOTHERMAL CRYSTALLIZATION; THERMAL-PROPERTIES; WATER SORPTION; ACID; FURAN; COPOLYESTERS;

D O I：

10.3389/fchem.2020.00585

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This critical review considers the extensive research and development dedicated, in the last years, to a single polymer, the poly(ethylene 2,5-furandicarboxylate), usually simply referred to as PEF. PEF importance stems from the fact that it is based on renewable resources, typically prepared from C6 sugars present in biomass feedstocks, for its resemblance to the high-performance poly(ethylene terephthalate) (PET) and in terms of barrier properties even outperforming PET. For the first time synthesis, properties, and end-life targeting-a more sustainable PEF-are critically reviewed. The emphasis is placed on how synthetic roots to PEF evolved toward the development of greener processes based on ring open polymerization, enzymatic synthesis, or the use of ionic liquids; together with a broader perspective on PEF end-life, highlighting recycling and (bio)degradation solutions.

引用

页数：18

共 109 条

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