Photoluminescence properties and thermal stability of samarium-doped barium phosphate phosphors

被引:33
作者
Chiang, Chung-Hao [1 ]
Fang, Ying-Chien [2 ]
Lin, Han-Yu [1 ]
Chu, Sheng-Yuan [1 ,3 ,4 ]
机构
[1] Natl Cheng Kung Univ, Dept Elect Engn, Tainan 70101, Taiwan
[2] Natl Cheng Kung Univ, Dept Mat Sci & Engn, Tainan 70101, Taiwan
[3] Natl Cheng Kung Univ, Ctr Micro Nano Sci & Technol, Tainan 70101, Taiwan
[4] Natl Cheng Kung Univ, Adv Optoelect Technol Ctr, Tainan 70101, Taiwan
关键词
Sm3+ activator; Orange-red emission; Phosphor-converted white light-emitting diodes (pc-WLEDs); LIGHT-EMITTING-DIODES; ENERGY-TRANSFER; LUMINESCENCE PROPERTIES; EMISSION; LIFETIME; SM3+; GAN;
D O I
10.1016/j.ceramint.2016.12.080
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this paper, Sm3+-doped Ca6BaP4O17 phosphors were synthesized via a conventional solid-state reaction method. Orange-red emission was observed from these phosphors under near-ultraviolet (UV) excitation at 405 nm. The luminescence properties of the obtained phosphors were characterized. The Ca6BaP4O17:Sm3+ phosphor can be efficiently excited by near-UV and blue light, and their emission spectrum consists of three emission peaks, at 567, 602, and 650 nm, respectively. The thermal stability of Ca6BaP4O17:Sm3+ phosphors was investigated systematically and corresponding mechanisms were proposed. Based on the results, the as prepared Ca6BaP4O17:Sm3+ phosphors are promising orange-red-emitting phosphors for near-UV-based white light-emitting diodes.
引用
收藏
页码:4353 / 4356
页数:4
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