Di-μ-chlorido-bis({2-[1-(2-pyridylethylimino)ethyl]pyrrolato-κ3N,N′,N"}copper(II))

被引：6

作者：

Li, Rongqing ^{[1
]}

Zhao, Pusu ^{[1
]}

Tang, Guodong ^{[1
]}

Tang, Xiaoling ^{[1
]}

机构：

[1] Huaiyin Teachers Coll, Jiangsu Key Lab Chem Low Dimens Mat, Huaian 223300, Jiangsu Prov, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2008年 / 64卷 / 10期

关键词：

D O I：

10.1107/S0108270108028783

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Cu(2)(C(13)H(14)N(3))(2)Cl(2)], is a neutral dimeric copper(II) complex. The two Cu(II) atoms are asymmetrically bridged by two chloride ions. Each Cu(II) atom is also bound to the three N atoms of a deprotonated tridentate Schiff base ligand, giving a distorted square-pyramidal N(3)Cl(2) coordination environment overall. The dinuclear complex lies across an inversion centre in the space group P (1) over bar. This work demonstrates the effect of ligand flexibility and steric constraints on the structures of copper(II) complexes.

引用

页码：M339 / M341

页数：3

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