TBHP-mediated highly efficient dehydrogenative cross-oxidative coupling of methylarenes with acetanilides

被引：6
作者：
Chen, Cui [1 ]
Liu, Weibing [1 ]
Zhou, Peng [1 ]
机构：
[1] Guangdong Univ Petrochem Technol, Coll Chem Engn, 2 Guandu Rd, Maoming 525000, Peoples R China
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 12卷
关键词：
dehydrogenative cross oxidative coupling; methyl arenes; N-arylbenzamides; TBHP; BOND FORMATION; ALDEHYDES; COPPER; ACCESS; AMIDES; INHIBITORS; ACYLATION; MILD;
D O I：
10.3762/bjoc.12.217
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A TBHP-mediated dehydrogenative cross-oxidative-coupling approach has been developed for the synthesis of N-arylbenzamides from methylarenes and acetanilides. This cross-coupling method is free of transition metal catalysts and ligands, and no extra organic solvents are required, which make it an useful and attractive strategy for the straightforward construction of C-N bonds. Besides, this conversion is an important complement to the conventional C-N forming strategies.
引用
收藏
页码：2250 / 2255
页数：6
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