Nonisocyanate polyurethane/silica hybrid coatings via a sol-gel route

被引：16

作者：

Hosgor, Z. ^{[2
]}

Kayaman-Apohan, N. ^{[1
]}

Karatas, S. ^{[1
]}

Gungor, A. ^{[1
]}

Menceloglu, Y. ^{[3
]}

机构：

[1] Marmara Univ, Dept Chem, Fac Art & Sci, TR-34722 Istanbul, Turkey

[2] Trakya Univ, Fac Art & Sci, Dept Chem, Edirne, Turkey

[3] Sabanci Univ, Fac Engn & Nat Sci, TR-34956 Istanbul, Turkey

来源：

ADVANCES IN POLYMER TECHNOLOGY | 2012年 / 31卷 / 04期

关键词：

Nonisocyanate route; Organic-inorganic hybrid; Phosphine oxide; Polyurethane; Sol-gel; PHOSPHORUS-CONTAINING EPOXY; FLAME-RETARDANT; PHOSPHINE OXIDE; SILICON; RESINS; NANOCOMPOSITES;

D O I：

10.1002/adv.20262

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Polyurethane/silica hybrids by a nonisocyanate route were prepared by reacting cyclic carbonate-modified bis(4-glycidyloxy phenyl)phenyl phosphine oxide (BGPPO), and poly(propyleneglycol)diglycidyl ether (PPG-DGE) with hexamethylene diamine. The incorporation of silica was achieved via a solgel method. The effect of silica and phosphine oxide moiety on polyurethane coating properties was studied by physical, mechanical, and thermal tests. Modulus and hardness of the coatings were enhanced by increasing the amount of silica and phosphine oxide based resin. The improvement in flame retardancy and thermal stability of nanocomposites was proved with increased char yield values and decomposition temperatures in thermogravimetric analyses. (C) 2011 Wiley Periodicals, Inc. Adv Polym Techn 31: 390400, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/adv.20262

引用

页码：390 / 400

页数：11

共 37 条

[1] Thermal stability and flame retardancy of polyurethanes [J].

Chattopadhyay, D. K. ;

Webster, Dean C. .

PROGRESS IN POLYMER SCIENCE, 2009, 34 (10) :1068-1133

[2] Preparation and thermal properties of a novel flame-retardant coating [J].

Chen, Xilei ;

Hu, Yuan ;

Jiao, Chuanmei ;

Song, Lei .

POLYMER DEGRADATION AND STABILITY, 2007, 92 (06) :1141-1150

[3] Structure and mechanical properties of polyurethane/silica hybrid coatings [J].

Chen, YC ;

Zhou, SX ;

Yang, HH ;

Wu, LM .

MACROMOLECULAR MATERIALS AND ENGINEERING, 2005, 290 (10) :1001-1008

[4] Synthesis, characterization and thermal properties of novel epoxy containing silicon and phosphorus nanocomposites by sol-gel method [J].

Chiang, CL ;

Ma, CCM .

EUROPEAN POLYMER JOURNAL, 2002, 38 (11) :2219-2224

[5]

Chuang K. C., 1995, HIGH PERFORM POLYM, V7, P81

[6] Solvent-free and nonisocyanate melt transurethane reaction for aliphatic polyurethanes and mechanistic aspects [J].

Deepa, P. ;

Jayakannan, M. .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (07) :2445-2458

[7] Non-isocyanate-based polyurethanes derived upon the reaction of amines with cyclocarbonate resins [J].

Diakoumakos, CD ;

Kotzev, DL .

MACROMOLECULAR SYMPOSIA, 2004, 216 :37-46

[8] Preparation and properties of halogen-free flame retardant epoxy resins with phosphorus-containing siloxanes [J].

Ding, Jiapei ;

Tao, Zhiqiang ;

Zuo, Xiaobiao ;

Fan, Lin ;

Yang, Shiyong .

POLYMER BULLETIN, 2009, 62 (06) :829-841

[9] A poly(ethylene glycol)-supported quaternary ammonium salt for highly efficient and environmentally friendly chemical fixation Of CO2 with epoxides under supercritical conditions [J].

Du, Y ;

Wang, JQ ;

Chen, JY ;

Cai, F ;

Tian, JS ;

Kong, DL ;

He, LN .

TETRAHEDRON LETTERS, 2006, 47 (08) :1271-1275

[10] Novel flame-retardant thermosets:: Phosphine oxide containing diglycidylether as curing agent of phenolic novolac resins [J].

Espinosa, MA ;

Galià, M ;

Càdiz, V .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (14) :3516-3526

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