A novel one-pot synthesis of 3-carbomethoxy-4-arylfuran-2-(5H)-ones from ketones using [hydroxy(tosyloxy)iodo]benzene

被引：22
作者：
Karade, Nandkishor N. [1 ]
Gampawar, Sumeet V. [1 ]
Kondre, Jeevan M. [1 ]
Shinde, Sandeep V. [1 ]
机构：
[1] Swami Ramanand Teerth Marathwada Univ, Sch Chem Sci, Nanded 431606, Maharashtra, India
来源：
TETRAHEDRON LETTERS | 2008年 / 49卷 / 28期
关键词：
hypervalent iodine; gamma-lactone; potassium monomethyl malonate; enolisable ketone;
D O I：
10.1016/j.tetlet.2008.05.012
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel one-pot procedure for the synthesis of 3-carbomethoxy-4-aryl furan-2-(5H)-ones is reported via alpha-tosyloxylation of enolisable ketones with [hydroxy(tosyloxy)iodo]benzene, followed by treatment with potassium monomethyl malonate and K2CO3. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4402 / 4404
页数：3
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