Phase-Sensitive Sum-Frequency Spectroscopy

被引：241

作者：

Shen, Y. R. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Phys, Berkeley, CA 94720 USA

来源：

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 64 | 2013年 / 64卷

关键词：

surfaces; interfaces; nonlinear susceptibilities; structures; interference; VIBRATIONAL SPECTROSCOPY; 2ND-HARMONIC GENERATION; VAPOR/WATER INTERFACE; ISOTOPIC DILUTION; WATER-MOLECULES; AQUEOUS ACID; SURFACE; ORIENTATION; SPECTRA; INTERFERENCE;

D O I：

10.1146/annurev-physchem-040412-110110

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phase-sensitive sum-frequency spectroscopy (SFS) allows the complete measurement of the complex spectra of surface nonlinear response coefficients. Similar to linear spectroscopy, the spectrum of the imaginary part of a surface response coefficient directly characterizes surface resonances without complication. This newly developed technique has greatly enhanced the capability of surface SFS and provides many new research opportunities for surface science. This article describes the experimental schemes and underlying theory for the technique and briefly reviews works that have clearly demonstrated its power.

引用

页码：129 / 150

页数：22

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