Density, viscosity and spectroscopic studies for the binary system of dipropylene glycol+1,2-ethylenediamine at T = (293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K

被引:17
作者
Zhang, Fei [1 ]
Liu, Xiaoyao [1 ]
Yang, Xinyu [1 ]
Liu, Lihua [1 ]
机构
[1] Inner Mongolia Univ Technol, Coll Chem Engn, Hohhot 010051, Peoples R China
关键词
Density; Viscosity; Excess Property; 1,2-ethanediamine; Dipropylene glycol; EXCESS MOLAR VOLUMES; PLUS DIMETHYL-SULFOXIDE; ETHYLENE-GLYCOL; AQUEOUS-SOLUTIONS; SULFUR-DIOXIDE; ABSORPTION PROCESSES; TRIETHYLENE GLYCOL; LIQUID MIXTURES; HEAT-CAPACITIES; 1,2-ETHANEDIAMINE;
D O I
10.1016/j.molliq.2016.08.040
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The density (rho) and viscosity (eta) data were measured on the binary system of dipropylene glycol (DPG) + 1,2-ethanediamine (EDA) with the different mole fractions at (293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) IC under atmospheric pressure. On the basis of the experimental rho and eta data, the excess molar volumes (V-m(E)) and dynamic viscosity deviations (Delta v) were calculated. Meanwhile, the Redlich-Kister type funetion was employed to calculate the coefficients and evaluate the standard deviation between the experimental and calculated data by using V-m(E) and Delta v values. After that, the intermolecular interactions between EDA and DPG was discussed according to FTIR and UV-vis spectral results. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:192 / 201
页数:10
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