Changing the activity of electrocatalysts for oxygen reduction by tuning the surface electronic structure

被引：1848
作者：
Stamenkovic, Vojislav
Mun, Bongjin Simon
Mayrhofer, Karl J. J.
Ross, Philip N.
Markovic, Nenad M.
Rossmeisl, Jan
Greeley, Jeff
Norskov, Jens K. [1 ]
机构：
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Sci Mat, Berkeley, CA 94720 USA
[2] Tech Univ Denmark, Dept Phys, Ctr Atom Scale Mat Phys, NanoDTU, DK-2800 Lyngby, Denmark
[3] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 18期
关键词：
alloys; density functional calculations; electrochemistry; oxygen; platinum;
D O I：
10.1002/anie.200504386
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Graph Presented) Going platinum: The theoretical description of electrocatalytic phenomena is extremely challenging. A simple, density functional theory based model has been developed that is able to give a semi-quantitative description of the reaction kinetics for the electrocatalytic oxygen reduction on several platinum binary alloys, Pt3M (see graph). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：2897 / 2901
页数：5
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