Solubility of terephthalic acid in aqueous N-methyl pyrrolidone and N,N-dimethyl acetamide solvents at (303.2 to 363.2) K

被引:23
作者
Guo, Xia [1 ]
Cheng, You-wei [1 ]
Wang, Li-jun [1 ]
Li, Xi [1 ]
机构
[1] Zhejiang Univ, Dept Chem Engn, Hangzhou 310027, Peoples R China
关键词
D O I
10.1021/je700635r
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental solubilities are reported for terephthalic acid (TA) in binary mixtures of N-methyl pyrrolidone (1) + water (2) and N,N-dimethyl acetamide (1) + water (2) in the temperature range of (303.2 to 363.2) K. The mole fraction of water in the N-methyl pyrrolidone + water solvent mixtures x(2) ranges from 0 to 0.5791 and in the N,N-dimethyl acetamide + water solvent mixtures X2 ranges from 0 to 0.5477. The experimental results show that the solubility of TA increases significantly with an increase in temperature and decreases significantly with an increase in X2. The solubility data were correlated by a modified Buchowski equation.
引用
收藏
页码:1421 / 1423
页数:3
相关论文
共 12 条
[1]   Spectroscopic analysis of organic contaminants in terephthalic acid: colour implications in poly(ethylene terephthalate) manufacture [J].
Allen, NS ;
Edge, M ;
Daniels, J ;
Royall, D .
POLYMER DEGRADATION AND STABILITY, 1998, 62 (02) :373-383
[2]   SOLVENT ACTIVITY ALONG A SATURATION LINE AND SOLUBILITY OF HYDROGEN-BONDING SOLIDS [J].
BUCHOWSKI, H ;
KSIAZCZAK, A ;
PIETRZYK, S .
JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (09) :975-979
[3]   Solubility of N-hydroxyphthalimide in binary acetic acid plus water solvent mixtures at (293.2 to 363.2) K [J].
Cheng, Youwei ;
Wang, Qinbo ;
Wang, Lijun ;
Li, Xi .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (03) :1025-1027
[4]   Optimum ratio of Co/Mn in the liquid-phase catalytic oxidation of p-xylene to terephthalic acid [J].
Cheng, YW ;
Li, X ;
Wang, LJ ;
Wang, QB .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (12) :4156-4162
[5]   Effects of guanidine on the liquid-phase catalytic oxidation of p-xylene to terephthalic acid [J].
Cheng, YW ;
Li, X ;
Wang, QB ;
Wang, LJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (20) :7756-7760
[6]  
DING G, 2007, THESIS ZHEJIANG U HA
[7]  
Lee F., 1999, U. S. Patent, Patent No. [5,961,935, 5961935]
[8]   Solubilities of terephthalaldehydic, p-toluic, benzoic, terephthalic, and isophthalic acids in N-methyl-2-pyrrolidone from 295.65 K to 371.35 K [J].
Li, DQ ;
Liu, DZ ;
Wang, FA .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (01) :172-173
[9]   METHODOLOGY AND SCOPE OF METAL BROMIDE AUTOXIDATION OF HYDROCARBONS [J].
PARTENHEIMER, W .
CATALYSIS TODAY, 1995, 23 (02) :69-158
[10]   BY-PRODUCT IDENTIFICATION IN THE TEREPHTHALIC ACID PRODUCTION PROCESS AND POSSIBLE MECHANISMS OF THEIR FORMATION [J].
ROFFIA, P ;
CALINI, P ;
MOTTA, L ;
TONTI, S .
INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1984, 23 (04) :629-634