Using a multi-theoretical framework, the present study analysed in a physical education setting the relationships between 2x2 achievement goals, friendship goals (approach-avoidance), basic psychological needs, intrinsic motivation, enjoyment, and physical self-concept. 421 students (231 males, 190 females) completed a questionnaire that included the Spanish validated versions of AGQ-PE, FGQ, BPNES and the subscales intrinsic motivation of the PLOC, physical self-concept of the DF-AF5, and enjoyment of the IMI. The modified structural equation model revealed that mastery-approach positively predicted the three basic psychological needs, and mastery-friendship positively predicted relationship. Psychological needs also predicted positively intrinsic motivation, which positively predicted enjoyment and physical self-concept. Results are discussed using as reference a multiple theoretical framework and practical implications are proposed