On the Use of Starch in Emulsion Polymerizations

被引：29

作者：

Cummings, Shidan ^{[1
]}

Zhang, Yujie ^{[1
]}

Smeets, Niels ^{[2
]}

Cunningham, Michael ^{[3
]}

Dube, Marc A. ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem & Biol Engn, Ctr Catalysis Res & Innovat, 161 Louis Pasteur Private, Ottawa, ON K1N 6N5, Canada

[2] McMaster Univ, Dept Chem Engn, 1280 Main St West, Hamilton, ON L8S 4L7, Canada

[3] Queens Univ, Dept Chem Engn, 19 Div St, Kingston, ON K7L 3N6, Canada

来源：

PROCESSES | 2019年 / 7卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

Starch; graft; polymerization; emulsion; polysaccharide; GRAFT CO-POLYMERIZATION; MICROWAVE-ASSISTED SYNTHESIS; NATIVE POTATO STARCH; METHYL-METHACRYLATE; MANGANIC PYROPHOSPHATE; MECHANICAL-PROPERTIES; ACRYLIC-ACID; SAGO STARCH; WAXY MAIZE; PHYSICOCHEMICAL PROPERTIES;

D O I：

10.3390/pr7030140

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The substitution of petroleum-based synthetic polymers in latex formulations with sustainable and/or bio-based sources has increasingly been a focus of both academic and industrial research. Emulsion polymerization already provides a more sustainable way to produce polymers for coatings and adhesives, because it is a water-based process. It can be made even more attractive as a green alternative with the addition of starch, a renewable material that has proven to be extremely useful as a filler, stabilizer, property modifier and macromer. This work provides a critical review of attempts to modify and incorporate various types of starch in emulsion polymerizations. This review focusses on the method of initiation, grafting mechanisms, starch feeding strategies and the characterization methods. It provides a needed guide for those looking to modify starch in an emulsion polymerization to achieve a target grafting performance or to incorporate starch in latex formulations for the replacement of synthetic polymers.

引用

页数：40

共 237 条

[1] SYNTHESIS AND CHARACTERIZATION OF STARCH-GLYCIDYL METHACRYLATE-ACRYLIC ACID CATION-EXCHANGE COMPOSITES [J].