Fabrication of low adhesive superhydrophobic surfaces using nano Cu/Al2O3 Ni-Cr composited electro-brush plating

Superhydrophobic nano Cu/Al2O3 Ni-Cr composited coating with a low adhesive force was deposited onto the Q345 carbon steel via electro-brush plating. Surface morphologies of nano Cu/Al2O3 Ni-Cr cornposited coating were investigated by scanning electron microscope (SEM). Chemical compositions were characterized by energy dispersive spectroscopy (EDS). First of all, by adjusting different process parameters such as working voltage, relative velocity, Cu particles concentration and plating time, we obtain the most optimal parameters: working voltage is 15 V, relative velocity is 4.8 m/min, Cu particles concentration is 5 g/L and plating time is 60s. Under the best process parameters, the water contact angle reaches to 156 degrees and a sliding angle is less than 2 degrees on the nano Cu/Al2O3 Ni-Cr coating. Then the mechanism of the superhydrophobic and low adhesion characteristic of this surface were explained by Cassie's model. Low adhesive force can be characterized by max rebound height of water droplet. As a result, to achieve low adhesive surface it is necessary to decrease the fraction of the solid/liquid interface under the water droplet. Finally the coating was proved to have an excellent self-cleaning performance. (C) 2015 Elsevier B.V. All rights reserved.