Microwave Synthesis of Nano-Sized SnO2 for Lithium-Ion Batteries

被引:2
作者
Yoshinaga, Masashi [1 ]
Kijima, Norihito [1 ]
Wakahara, Sonoko [1 ]
Akimoto, Junji [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
来源
ELECTROCERAMICS IN JAPAN XIV | 2011年 / 485卷
关键词
SnO2; nanoparticles; microwave synthesis; lithium-ion batteries; electrochemical property; OXIDE;
D O I
10.4028/www.scientific.net/KEM.485.127
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SnO2 nanoparticles were successfully synthesized by the microwave heating. The crystallite size of the SnO2 nanoparticles was estimated to be about 3 nm from the Scherre's equation. The initial lithium insertion capacity of the SnO2 nanoparticles was 2110 mAh/g which is larger than that of the micro-sized commercial SnO2 product. The rechargeable capacity at 10 cycles was 1060 mAh/g, and the capacity retention over the tenth cycles was about 50
引用
收藏
页码:127 / 130
页数:4
相关论文
共 6 条
[1]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[2]   Electrochemical and in situ x-ray diffraction studies of the reaction of lithium with tin oxide composites [J].
Courtney, IA ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (06) :2045-2052
[3]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[4]   Characterization and electrochemical property of α-Fe2O3 nanoparticles prepared by microwave heating [J].
Kijima, Norihito ;
Takahashi, Yasuhiko ;
Hayakawa, Hiroshi ;
Awaka, Junji ;
Akimoto, Junji .
CHEMISTRY LETTERS, 2007, 36 (04) :568-569
[5]   Microwave synthesis, characterization, and electrochemical properties of α-Fe2O3 nanoparticles [J].
Kijima, Norihito ;
Yoshinaga, Masashi ;
Awaka, Junji ;
Akimoto, Junji .
SOLID STATE IONICS, 2011, 192 (01) :293-297
[6]   Novel microwave synthesis of nanocrystalline SnO2 and its electrochemical properties [J].
Subramanian, V. ;
Burke, William W. ;
Zhu, Hongwei ;
Wei, Bingqing .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (12) :4550-4556