Phase-dependence of gold nanoparticle dispersibility in blue phase and chiral nematic liquid crystals

被引:18
作者
Yoshida, Hiroyuki [1 ,2 ]
Inoue, Kenta [1 ]
Kubo, Hitoshi [1 ]
Ozaki, Masanori [1 ]
机构
[1] Osaka Univ, Div Elect Elect & Informat Engn, Suita, Osaka 5650871, Japan
[2] Japan Sci & Technol Corp JST, PRESTO, Kawaguchi, Saitama 3320012, Japan
关键词
OPTICAL-PROPERTIES; BULK METAMATERIAL; DISCLINATIONS; DISPLAYS; NANORODS; INDEX;
D O I
10.1364/OME.3.000842
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We investigate the dispersibility of spherical gold nanoparticles in three phases of a chiral liquid crystal - blue phase I, blue phase II and the cholesteric phase - by UV-visible spectroscopy and optical microscopy. UV-visible spectroscopy revealed that a gradual red-shift and broadening of local surface plasmon resonance occur in the blue I and cholesteric phases. Moreover, optical microscopy revealed a clear difference in the aggregation behavior of nanoparticles depending on the phase, with uniform textures being observed in the blue II phase, and agglomerates forming in blue I and cholesteric phases. The difference in the dispersibility of nanoparticles is discussed in terms of the structure of each liquid crystal phase. (C) 2013 Optical Society of America
引用
收藏
页码:842 / 852
页数:11
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