Oxidation of cyclohexene by dendritic PAMAMSA-Mn(II) complexes

被引：45

作者：

Yang, ZW ^{[1
]}

Kang, QX ^{[1
]}

Ma, HC ^{[1
]}

Li, CL ^{[1
]}

Lei, ZQ ^{[1
]}

机构：

[1] NW Normal Univ, Coll Chem & Chem Engn, Gansu Key Lab Polymer Mat, Lanzhou 730070, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 213卷 / 02期

基金：

中国国家自然科学基金;

关键词：

dendrimer; complexes; catalysis; oxidation; cyclohexene;

D O I：

10.1016/j.molcata.2003.12.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Six dendritic PAMAMSA-Mn (II) complexes were synthesized and were well characterized. The oxidation of cyclohexene under 1 atmospheric pressure of molecular oxygen in the absence of any solvent with the synthesized complexes was employed to value their catalytic properties. It was shown that all the dendritic complexes with different generation numbers (G) exhibit promising catalytic activities for the oxidation. Under the mild condition, all the oxidations give 7-oxabicyclo[4,1,0]heptane 1, 2-cyclohexen-2-ol 2, 2-cyclohexen-2-one 3 and 7-oxabicyclo [4,1,0]heptan-2-one 4 as the major products. The factors that affect the oxidations were also well investigated under identical conditions. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：169 / 176

页数：8

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