PtBS-b-P4VP and PTMSS-b-P4VP Isoporous Integral-Asymmetric Membranes with High Thermal and Chemical Stability

被引：43
作者：
Hahn, Janina [1 ]
Filiz, Volkan [1 ]
Rangou, Sofia [1 ]
Lademann, Brigitte [1 ]
Buhr, Kristian [1 ]
Clodt, Juliana I. [1 ]
Jung, Adina [1 ]
Abetz, Clarissa [1 ]
Abetz, Volker [1 ]
机构：
[1] Helmholtz Zentrum Geesthacht, Polymer Res Inst, D-21502 Geesthacht, Germany
来源：
MACROMOLECULAR MATERIALS AND ENGINEERING | 2013年 / 298卷 / 12期
关键词：
anionic polymerization; diblock copolymers; membranes; self-assembly; thermal properties; DIBLOCK COPOLYMER MEMBRANES; BLOCK-COPOLYMER; NANOPOROUS MEMBRANES; DRUG-DELIVERY; WATER-PURIFICATION; FILMS; NANOCHANNELS; TECHNOLOGY; SCATTERING; SCIENCE;
D O I：
10.1002/mame.201300012
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Isoporous integral-asymmetric membranes of tailor-made poly(tert-butylstyrene)- and poly(4-trimethylsilylstyrene)-block-poly(4-vinylpyridine) diblock copolymers are reported here for the first time. The membrane development involved the optimization of the production processwhich is a combination of block copolymer self-assembly and the non-solvent induced phase inversion process. The membranes showed an improved thermal and chemical stability compared to previously reported polystyrene-block-poly(4-vinylpyridine) membranes, thus the number of potential application areas for such type of isoporous membranes is increased.
引用
收藏
页码：1315 / 1321
页数：7
相关论文
共 29 条
[1]  
Brandrup J., 1999, Polymer Handbook, VII
[2]   Measurements of the Flory-Huggins interaction parameter for polystyrene-poly(4-vinylpyridine) blends [J].
Clarke, CJ ;
Eisenberg, A ;
LaScala, J ;
Rafailovich, MH ;
Sokolov, J ;
Li, Z ;
Qu, S ;
Nguyen, D ;
Schwarz, SA ;
Strzhemechny, Y ;
Sauer, BB .
MACROMOLECULES, 1997, 30 (14) :4184-4188
[3]   Double Stimuli-Responsive Isoporous Membranes via Post-Modification of pH-Sensitive Self-Assembled Diblock Copolymer Membranes [J].
Clodt, Juliana Isabel ;
Filiz, Volkan ;
Rangou, Sofia ;
Buhr, Kristian ;
Abetz, Clarissa ;
Hoeche, Daniel ;
Hahn, Janina ;
Jung, Adina ;
Abetz, Volker .
ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (06) :731-738
[4]   Carbohydrates as Additives for the Formation of Isoporous PS-b-P4VP Diblock Copolymer Membranes [J].
Clodt, Juliana Isabel ;
Rangou, Sofia ;
Schroeder, Anne ;
Buhr, Kristian ;
Hahn, Janina ;
Jung, Adina ;
Filiz, Volkan ;
Abetz, Volker .
MACROMOLECULAR RAPID COMMUNICATIONS, 2013, 34 (02) :190-194
[5]   Thin Film Self-Assembly of Poly(trimethylsilylstyrene-b-D,L-lactide) with Sub-10 nm Domains [J].
Cushen, Julia D. ;
Bates, Christopher M. ;
Rausch, Erica L. ;
Dean, Leon M. ;
Zhou, Sunshine X. ;
Willson, C. Grant ;
Ellison, Christopher J. .
MACROMOLECULES, 2012, 45 (21) :8722-8728
[6]   Solution Small-Angle X-ray Scattering as a Screening and Predictive Tool in the Fabrication of Asymmetric Block Copolymer Membranes [J].
Dorin, Rachel Mika ;
Marques, Debora Salomon ;
Sai, Hiroaki ;
Vainio, Ulla ;
Phillip, William A. ;
Peinemann, Klaus-Viktor ;
Nunes, Suzana P. ;
Wiesner, Ulrich .
ACS MACRO LETTERS, 2012, 1 (05) :614-617
[7]   Impacts of polystyrene molecular weight and modification to the repeat unit structure on the glass transition-nanoconfinement effect and the cooperativity length scale [J].
Ellison, CJ ;
Mundra, MK ;
Torkelson, JM .
MACROMOLECULES, 2005, 38 (05) :1767-1778
[8]   Water Purification by Membranes: The Role of Polymer Science [J].
Geise, Geoffrey M. ;
Lee, Hae-Seung ;
Miller, Daniel J. ;
Freeman, Benny D. ;
Mcgrath, James E. ;
Paul, Donald R. .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2010, 48 (15) :1685-1718
[9]   Structure formation of integral-asymmetric membranes of polystyrene-block-Poly(ethylene oxide) [J].
Hahn, Janina ;
Filiz, Volkan ;
Rangou, Sofia ;
Clodt, Juliana ;
Jung, Adina ;
Buhr, Kristian ;
Abetz, Clarissa ;
Abetz, Volker .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 2013, 51 (04) :281-290
[10]   Nanoporous Membranes Derived from Block Copolymers: From Drug Delivery to Water Filtration [J].
Jackson, Elizabeth A. ;
Hillmyer, Marc A. .
ACS NANO, 2010, 4 (07) :3548-3553
123