Effect of Surface Modification on the Hansen Solubility Parameters of Single-Walled Carbon Nanotubes

被引:22
|
作者
Ma, Jing [1 ]
Larsen, Raino Mikael [1 ]
机构
[1] Aalborg Univ, Dept Mech & Mfg Engn, DK-9220 Aalborg, Denmark
关键词
X-RAY PHOTOELECTRON; MECHANICAL-PROPERTIES; DISPERSION; XPS; ADSORPTION; SOLVENTS;
D O I
10.1021/ie302950u
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this work, seven types of surface-modified single-walled carbon nanotubes (SWNTs) were studied by X-ray photoelectron spectroscopy (U'S) and Raman spectroscopy to investigate the functional groups and extent of functionalization. Hansen solubility parameters were determined based on observations of the sedimentation and swollen states of the SWNTs in solvents after ultrasonication, and the results were compared with the hydrodynamic sizes of the SWNTs evaluated by the dynamic light scattering method. We found that the solubility of SWNTs is related to their functional groups and degree of functionalization, as well as their size.
引用
收藏
页码:3514 / 3521
页数:8
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