Effect of intramolecular hydrogen bonding on biomimetic reactions by flavins

被引：1

作者：

Geetanjali ^{[1
]}

Singh, Ram ^{[2
]}

机构：

[1] Univ Delhi, Dept Chem, Kirori Mal Coll, Delhi 110007, India

[2] Delhi Technol Univ, Dept Appl Chem & Polymer Technol, Delhi, India

来源：

HETEROCYCLIC COMMUNICATIONS | 2013年 / 19卷 / 04期

关键词：

biomimetic reactions; flavin; hydrogen bonding; thioanisole; 10-SUBSTITUTED ISOALLOXAZINES; SOLID ACIDS; 4A-HYDROPEROXYFLAVIN; CATALYSIS; OXIDATION; AMINES; OXYGEN;

D O I：

10.1515/hc-2013-0022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Selected 6- and 7-carboxyflavins activate H2O2, oxidizing thioanisole to its sulfoxide. The greater reactivity of the 6-carboxyflavin derivatives are ascribed to the intramolecular hydrogen bonding between N(5) and the carboxyl group of the flavin system.

引用

页码：261 / 263

页数：3

共 14 条

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