A molybdenum diphosphonate network structure exhibiting reversible dehydration and selective uptake of methanol

被引：10

作者：

Ayi, Ayi A. ^{[1
,2
]}

Burrows, Andrew D. ^{[1
]}

Mahon, Mary F. ^{[1
]}

Sebestyen, Viorica M. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] Univ Calabar, Dept Pure & Appl Chem, Calabar, Nigeria

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 45期

基金：

英国工程与自然科学研究理事会;

关键词：

CRYSTAL-STRUCTURE DETERMINATION; METAL-ORGANIC FRAMEWORKS; POWDER DIFFRACTION DATA; HYDROTHERMAL SYNTHESIS; COORDINATION POLYMERS; HYBRID MATERIALS; ACID;

D O I：

10.1039/c3ce40484f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new molybdenum diphosphonate network structure has been prepared and structurally characterised. It shows reversible dehydration, which occurs with a structural change. The dehydrated material is able to adsorb methanol but not ethanol.

引用

页码：9301 / 9303

页数：3

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