Sustainable valorization of asphaltenes via flash joule heating

被引:39
作者
Saadi, M. A. S. R. [1 ]
Advincula, Paul A. [2 ]
Thakur, Md Shajedul Hoque [1 ]
Khater, Ali Zein [1 ]
Saad, Shabab [3 ]
Zeraati, Ali Shayesteh [3 ]
Nabil, Shariful Kibria [3 ]
Zinke, Aasha [1 ]
Roy, Soumyabrata [1 ]
Lou, Minghe [4 ]
Bheemasetti, Sravani N. [5 ,6 ]
Al Bari, Md Abdullah [3 ]
Zheng, Yiwen [7 ]
Beckham, Jacob L. [2 ]
Gadhamshetty, Venkataramana [5 ,6 ]
Vashisth, Aniruddh [7 ]
Kibria, Md Golam [3 ]
Tour, James M. [1 ,2 ]
Ajayan, Pulickel M. [1 ]
Rahman, Muhammad M. [1 ]
机构
[1] Rice Univ, Dept Mat Sci & NanoEngn, Houston, TX 77005 USA
[2] Rice Univ, Dept Chem, Houston, TX 77005 USA
[3] Univ Calgary, Dept Chem & Petr Engn, Calgary, AB T2N 1N4, Canada
[4] Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA
[5] South Dakota Sch Mines & Technol, Dept Civil & Environm Engn, Rapid City, SD 57701 USA
[6] Two Dimens Mat Biofilm Engn Sci & Technol 2D BEST, Rapid City, SD 57701 USA
[7] Univ Washington, Dept Mech Engn, Seattle, WA 98195 USA
关键词
POROUS CARBON NANOSHEET; MECHANICAL-PROPERTIES; GRAPHENE; PETROLEUM; STRENGTH; ELECTRODE; GRAPHITE; REAXFF;
D O I
10.1126/sciadv.add3555
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The refining process of petroleum crude oil generates asphaltenes, which poses complicated problems during the production of cleaner fuels. Following refining, asphaltenes are typically combusted for reuse as fuel or discarded into tailing ponds and landfills, leading to economic and environmental disruption. Here, we show that low-value asphaltenes can be converted into a high-value carbon allotrope, asphaltene-derived flash graphene (AFG), via the flash joule heating (FJH) process. After successful conversion, we develop nanocomposites by dispersing AFG into a polymer effectively, which have superior mechanical, thermal, and corrosion-resistant properties compared to the bare polymer. In addition, the life cycle and technoeconomic analysis show that the FJH process leads to reduced environmental impact compared to the traditional processing of asphaltene and lower production cost compared to other FJH precursors. Thus, our work suggests an alternative pathway to the existing asphaltene processing that directs toward a higher value stream while sequestering downstream emissions from the processing.
引用
收藏
页数:15
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