A Catenane Assembled through a Single Charge-Assisted Halogen Bond

被引：65
|
作者：
Gilday, Lydia C. [1 ]
Lang, Thomas [1 ]
Caballero, Antonio [1 ]
Costa, Paulo J. [2 ,3 ]
Felix, Vitor [2 ,3 ]
Beer, Paul D. [1 ]
机构：
[1] Univ Oxford, Dept Chem, Inorgan Chem Lab, Oxford OX1 3QR, England
[2] Univ Aveiro, CICECO, Dept Quim, P-3810193 Aveiro, Portugal
[3] Univ Aveiro, Seccao Autonoma Ciencias Saude, P-3810193 Aveiro, Portugal
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 16期
基金：
欧洲研究理事会; 英国工程与自然科学研究理事会;
关键词：
catenanes; halogen bonding; supramolecular chemistry; template synthesis; ANION RECOGNITION; ROTAXANE; COMPLEXES;
D O I：
10.1002/anie.201300464
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Getting connected: The formation of pseudorotaxane assemblies between a designed macrocyclic halogen bonding (XB) acceptor (red in scheme) and a series of XB donor threading components was templated by a single halogen bond. The strength of the XB assembly between the pyridine macrocycle and iodopyridinium thread was utilized in the ring-closing metathesis clipping synthesis of a [2]catenane. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4356 / 4360
页数：5
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