Pd/C-Catalyzed Highly Efficient and Green Suzuki Cross-Coupling Reaction

被引：6
|
作者：
Chu, Wenyi [1 ,2 ]
Wang, Man [1 ,2 ]
Li, Xinmin [1 ,2 ]
Hou, Yanjun [1 ,2 ]
Sun, Zhizhong [1 ,2 ]
机构：
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
[2] Coll Heilongjiang Prov, Key Lab Chem Engn Proc & Technol Highefficiency C, Harbin 150080, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 32卷 / 09期
关键词：
Pd/C; Suzuki reaction; biphenyls; ionic liquid; LIGAND-FREE; HETEROGENEOUS PALLADIUM; ARYLBORONIC ACIDS; ARYL; COMPLEXES; HALIDES; SONOGASHIRA; HETEROARYL; CHLORIDES; CARBON;
D O I：
10.6023/cjoc201206029
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient protocol for the Suzuki reaction catalyzed by Pd/C has been developed in a green sovent. This method is able to prepare a variety of biaryls in high yields. In the presence of 1-butyl-3-methylimidazolium bis[(trifluoromethyl)sulfonyl]imide, the cross-coupling reaction of aryl bromides with arylboronic acids proceed smoothly in PEG400 aqueous at 45 degrees C. The catalyst could be recycled four times without loss of activity.
引用
收藏
页码：1666 / 1672
页数：7
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