Tailoring physical properties of carbon nanotube threads during assembly

被引:32
作者
Alvarez, Noe T. [1 ]
Miller, Peter [2 ]
Haase, Mark R. [2 ]
Lobo, Rui [3 ]
Malik, Rachit [2 ]
Shanov, Vesselin [2 ]
机构
[1] Univ Cincinnati, Chem Dept, Cincinnati, OH 45221 USA
[2] Univ Cincinnati, Biomed Chem & Environm Engn, Cincinnati, OH 45221 USA
[3] Univ Nova Lisboa, Fac Ciencias & Tecnol, CTS UNINOVA, Nanophys & Energy Efficiency Grp GNCN,Dept Fis, P-2829516 Caparica, Portugal
关键词
Carbon nanotubes; Threads; Fibers; Yarns; Diameter control; Resistivity; Twist angle; FIBERS; STRENGTH; YARNS; SPUN; DIAMETER; DENSITY; NUMBER; WALLS; WIRES; NEAT;
D O I
10.1016/j.carbon.2018.11.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Spinnable carbon nanotubes (CNTs) are useful formats for studying physical properties of CNT fiber assemblies in their pristine states. They are free of catalyst, uniform in length, with a comparatively narrow diameter distribution, and their assembly into thread does not require additional chemicals or solvents. Good quality drawable CNT arrays can be readily assembled into uniform diameter threads with great control over the number of CNTs incorporated into the thread assembly. This uniformity allows study the physical properties that result from changes that occur during thread formation. Here, we report trends of electrical resistivity and mechanical strength that resulted from alterations in their manufacturing parameters, allowing to change intrinsic physical properties of a material such as electrical resistivity. We correlate the electrical resistivity and mechanical strength as a function of diameter, density, and turns/meter. Understanding the effects of dry-spinning parameters will allow a better design of the physical properties of CNT threads for specific applications, such as strain or electrochemical sensors. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:55 / 62
页数:8
相关论文
共 48 条
[1]   Nanometre-size tubes of carbon [J].
Ajayan, PM ;
Ebbesen, TW .
REPORTS ON PROGRESS IN PHYSICS, 1997, 60 (10) :1025-1062
[2]  
Alvarez N.T., 2013, WSEAS Proc.: Recent Adv. in Circuits, P336
[3]   Carbon nanotube assembly at near-industrial natural-fiber spinning rates [J].
Alvarez, Noe T. ;
Miller, Peter ;
Haase, Mark ;
Kienzle, Nicholas ;
Zhang, Lu ;
Schulz, Mark J. ;
Shanov, Vesselin .
CARBON, 2015, 86 :350-357
[4]   Polymer Coating of Carbon Nanotube Fibers for Electric Microcables [J].
Alvarez, Noe T. ;
Ochmann, Timothy ;
Kienzle, Nicholas ;
Ruff, Brad ;
Haase, Mark R. ;
Hopkins, Tracy ;
Pixley, Sarah ;
Mast, David ;
Schulz, Mark J. ;
Shanov, Vesselin .
NANOMATERIALS, 2014, 4 (04) :879-893
[5]   Uniform Large Diameter Carbon Nanotubes in Vertical Arrays from Premade Near-Monodisperse Nanoparticles [J].
Alvarez, Noe T. ;
Li, Feng ;
Pint, Cary L. ;
Mayo, John T. ;
Fisher, Ezekial Z. ;
Tour, James M. ;
Colvin, Vicki L. ;
Hauge, Robert H. .
CHEMISTRY OF MATERIALS, 2011, 23 (15) :3466-3475
[6]   Carbon nanotube bundles with tensile strength over 80 GPa [J].
Bai, Yunxiang ;
Zhang, Rufan ;
Ye, Xuan ;
Zhu, Zhenxing ;
Xie, Huanhuan ;
Shen, Boyuan ;
Cai, Dali ;
Liu, Bofei ;
Zhang, Chenxi ;
Jia, Zhao ;
Zhang, Shenli ;
Li, Xide ;
Wei, Fei .
NATURE NANOTECHNOLOGY, 2018, 13 (07) :589-+
[7]   Key Factors Limiting Carbon Nanotube Yarn Strength: Exploring Processing-Structure-Property Relationships [J].
Beese, Allison M. ;
Wei, Xiaoding ;
Sarkar, Sourangsu ;
Ramachandramoorthy, Rajaprakash ;
Roenbeck, Michael R. ;
Moravsky, Alexander ;
Ford, Matthew ;
Yavari, Fazel ;
Keane, Denis T. ;
Loutfy, Raouf O. ;
Nguyen, SonBinh T. ;
Espinosa, Horacio D. .
ACS NANO, 2014, 8 (11) :11454-11466
[8]   Strong, Light, Multifunctional Fibers of Carbon Nanotubes with Ultrahigh Conductivity [J].
Behabtu, Natnael ;
Young, Colin C. ;
Tsentalovich, Dmitri E. ;
Kleinerman, Olga ;
Wang, Xuan ;
Ma, Anson W. K. ;
Bengio, E. Amram ;
ter Waarbeek, Ron F. ;
de Jong, Jorrit J. ;
Hoogerwerf, Ron E. ;
Fairchild, Steven B. ;
Ferguson, John B. ;
Maruyama, Benji ;
Kono, Junichiro ;
Talmon, Yeshayahu ;
Cohen, Yachin ;
Otto, Marcin J. ;
Pasquali, Matteo .
SCIENCE, 2013, 339 (6116) :182-186
[9]   Carbon nanotube-based neat fibers [J].
Behabtu, Natnael ;
Green, Micah J. ;
Pasquali, Matteo .
NANO TODAY, 2008, 3 (5-6) :24-34
[10]   Scale and twist effects on the strength of nanostructured yarns and reinforced composites [J].
Beyerlein, I. J. ;
Porwal, P. K. ;
Zhu, Y. T. ;
Hu, K. ;
Xu, X. F. .
NANOTECHNOLOGY, 2009, 20 (48)