Hydrogen Activation by an Intramolecular Boron Lewis Acid/Zirconocene Pair

被引：43

作者：

Podiyanachari, Santhosh Kumar ^{[1
]}

Froehlich, Roland ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Petersen, Jeffrey L. ^{[2
]}

Mueck-Lichtenfeld, Christian ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[2] W Virginia Univ, Bennett Dept Chem, Morgantown, WV 26506 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 35期

关键词：

boron; frustrated Lewis pairs; hydrogen activation; oxidative addition; zirconium; CENTER-DOT F; BIS(PENTAFLUOROPHENYL)BORANE; CATALYST; TRIS(PENTAFLUOROPHENYL)BORANE; 1,1-CARBOBORATION; HYDROZIRCONATION; TITANOCENE; COMPLEXES; CHEMISTRY; ALCOHOLS;

D O I：

10.1002/anie.201202218

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Let's split: Reaction of the zirconium complex A with Piers' borane [HB(C 6F 5) 2] yields the unusual borylalkyne zirconocene complex B which reacts with dihydrogen, activating it to give the doubly hydrido bridged alkyne zirconium complex C. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8830 / 8833

页数：4

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