Suzuki Cross-Coupling Reaction Catalyzed by the Palladium Complex Pd[N-MorphC(S)NP(O)(OiPr)2-O,S]2

被引：8

作者：

Safin, Damir A. ^{[1
,2
]}

Babashkina, Maria G. ^{[1
,2
]}

Klein, Axel ^{[2
]}

机构：

[1] Kazan VI Lenin State Univ, AM Butlerov Chem Inst, Kazan 420008, Russia

[2] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

来源：

CATALYSIS LETTERS | 2009年 / 129卷 / 3-4期

关键词：

Cross-coupling; Phenylboronic acid; Phenyl bromide; Suzuki-Miyaura reaction; N-Phosphorylthiourea; Palladium; INTRAMOLECULAR HYDROGEN-BOND; N-PHOSPHORYL-N'-(R)-THIOUREAS; PD(II); 1,5-O,S-COORDINATION; COORDINATION;

D O I：

10.1007/s10562-008-9778-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Suzuki cross-coupling reaction between phenyl bromide and phenylboronic acid, catalyzed by the palladium complex Pd[N-MorphC(S)NP(O)(OiPr)(2)-1,5-O,S)](2) in acetonitrile, toluene, THF or DMF has been investigated. Bases employed for the reaction were Na2CO3, K2CO3 or Cs2CO3. Varying largely the experimental conditions we found that excellent yields of the product were obtained using toluene and K2CO3 at 100 A degrees C at the catalyst amount of 0.02 mmol.

引用

页码：363 / 366

页数：4

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