共 45 条
Intrinsically self-healable, stretchable thermoelectric materials with a large ionic Seebeck effect
被引:143
作者:

Akbar, Zico Alaia
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机构:
Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engin Eering, 50 UNIST Gil, Ulsan 44919, South Korea
Kookmin Univ, Dept Chemistiy, 77 Jeongneung Ro, Seoul 136702, South Korea Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engin Eering, 50 UNIST Gil, Ulsan 44919, South Korea

Jeon, Ju-Won
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Kookmin Univ, Dept Chemistiy, 77 Jeongneung Ro, Seoul 136702, South Korea Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engin Eering, 50 UNIST Gil, Ulsan 44919, South Korea

Jang, Sung-Yeon
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机构:
Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engin Eering, 50 UNIST Gil, Ulsan 44919, South Korea Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engin Eering, 50 UNIST Gil, Ulsan 44919, South Korea
机构:
[1] Ulsan Natl Inst Sci & Technol UNIST, Sch Energy & Chem Engin Eering, 50 UNIST Gil, Ulsan 44919, South Korea
[2] Kookmin Univ, Dept Chemistiy, 77 Jeongneung Ro, Seoul 136702, South Korea
基金:
新加坡国家研究基金会;
关键词:
CONDUCTIVITY;
COMPOSITES;
POLYMERS;
BEHAVIOR;
D O I:
10.1039/c9ee03861b
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
While the thermoelectric (TE) generator has attracted tremendous attention, the development of wearable TE generators with stretchability and self-healability has been a significant challenge. Herein, we report intrinsically self-healable and stretchable ternary ionic TE hybrid materials, composed of a conjugated polymer (polyaniline), a non-conjugated anionic polyelectrolyte (poly(2-acrylamido-2-methyl-1-propanesulfonic acid)), and phytic acid. The proposed materials exhibit an excellent ionic figure-of-merit (ZT(i)) as well as remarkable stretchability (up to similar to 750%) and autonomous self-healability without any external stimuli. The ionic TE performance was sustainable under severe deformation (50% strain) and multiple self-healing processes (30 cycles), which is the first demonstration of such performance. The ZT(i) of the stretchable and self-healable ternary TE hybrids is 1.04. Moreover, a self-healable and stretchable ionic thermoelectric capacitor device is also demonstrated using the ternary TE hybrid.
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页码:2915 / 2923
页数:9
相关论文
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