Synthesis of a starch-based sulfonic ion exchange resin and adsorption of dyestuffs to the resin

被引:69
作者
Zhang, Hao [1 ,2 ]
Li, Yaxing [1 ,2 ]
Cheng, Bowen [2 ]
Ding, Changkun [2 ,3 ]
Zhang, Yi [1 ]
机构
[1] Tiangong Univ, Sch Text Sci & Engn, Tianjin 300387, Peoples R China
[2] Tiangong Univ, State Key Lab Separat Membranes & Membrane Proc, Tianjin 300387, Peoples R China
[3] Tiangong Univ, Sch Mat Sci & Engn, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
Starch resin; Ion exchange; Dyestuff absorption; IN-SITU ATTACHMENT; AQUEOUS-SOLUTIONS; CATIONIC DYES; EFFICIENT ADSORPTION; RHODAMINE-B; CONGO RED; REMOVAL; ACID; WASTE; KINETICS;
D O I
10.1016/j.ijbiomac.2020.06.017
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A starch-based ion exchange resin (SIR) was synthesized by copolymerizing raw starch with sodium medially( sulfonate and styrene. The structural and surface properties of the SIR were characterized by C-13 nuclear magnetic resonance spectroscopy, Fourier-transform infrared spectroscopy, gel permeation chromatography, scanning electron microscopy. X-ray diffractometry, thermogravimetric analysis, Brunauer-Emmett-Teller surface area analysis, and laser particle size analysis. The SIR was physicochemically and thermally stable and resistant to acids, bases, and enzymes. In static adsorption tests, the SIR had decolorization ratios (DRs) for mixed dyestuffs in wastewater of up to 84.04%, which was higher than the DR for a synthetic ion exchange resin (001 x 7, DR 77.14%). In dynamic adsorption tests, the SIR bed had a DR of 99.85% and a wastewater handling capacity 25 times the column volume. After three adsorption-regeneration cycles, the DR of the resin bed had decreased by <7.5%. The properties of the SIR, particularly the adaptability of the SIR to continuous column adsorption, make the SIR suitable for removing dyestuffs from industrial wastewater and a potential substitute for traditional sorbents such as activated carbon and synthetic resins. (C) 2020 Elsevier B.V. All rights reserved.
引用
收藏
页码:561 / 572
页数:12
相关论文
共 74 条
[51]   Systematic synthesis of pectin-g-(sodium acrylate-co-N-isopropylacrylamide) interpenetrating polymer network for superadsorption of dyes/M(II): determination of physicochemical changes in loaded hydrogels [J].
Singha, Nayan Ranjan ;
Karmakar, Mrinmoy ;
Mahapatra, Manas ;
Mondal, Himarati ;
Dutta, Arnab ;
Roy, Chandan ;
Chattopadhyay, Pijush Kanti .
POLYMER CHEMISTRY, 2017, 8 (20) :3211-3237
[52]   Construction of blood compatible chitin/graphene oxide composite aerogel beads for the adsorption of bilirubin [J].
Song, Xi ;
Huang, Xiuhong ;
Li, Zhixiong ;
Li, Zhentao ;
Wu, Keke ;
Jiao, Yanpeng ;
Zhou, Changren .
CARBOHYDRATE POLYMERS, 2019, 207 :704-712
[53]   Evaluating ion exchange resin efficiency and oxidative capacity for the separation of uranium(IV) and uranium(VI) [J].
Stoliker, Deborah L. ;
Kaviani, Nazila ;
Kent, Douglas B. ;
Davis, James A. .
GEOCHEMICAL TRANSACTIONS, 2013, 14
[54]   Ultrasonic modification of starch - Impact on granules porosity [J].
Sujka, Monika .
ULTRASONICS SONOCHEMISTRY, 2017, 37 :424-429
[55]   Biopolymers composites with peanut hull waste biomass and application for Crystal Violet adsorption [J].
Tahir, Noor ;
Bhatti, Haq Nawaz ;
Iqbal, Munawar ;
Noreen, Saima .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2017, 94 :210-220
[56]   Dye adsorption by self-recoverable, adjustable amphiphilic graphene aerogel [J].
Tang, Sheng ;
Xia, Dasha ;
Yao, Yao ;
Chen, Tianyu ;
Sun, Jun ;
Yin, Yijie ;
Shen, Wei ;
Peng, Yinxian .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2019, 554 :682-691
[57]   Preparation, characterisation and properties of sulphoxide modified polystyrene resins for solid-phase extraction of PtIV, RuIII and RuIV from hydrochloric acid [J].
Trautmann, Michael ;
Lubahn, Susanne ;
Holdt, Hans-Juergen .
REACTIVE & FUNCTIONAL POLYMERS, 2014, 83 :84-97
[58]   Adsorption of cefotaxime sodium salt on polymer coated ion exchange resin microparticles: Kinetics, equilibrium and thermodynamic studies [J].
Vasiliu, S. ;
Bunia, I. ;
Racovita, S. ;
Neagu, V. .
CARBOHYDRATE POLYMERS, 2011, 85 (02) :376-387
[59]   A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters [J].
Verma, Akshaya Kumar ;
Dash, Rajesh Roshan ;
Bhunia, Puspendu .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2012, 93 (01) :154-168
[60]   Synthesis of a novel 3,5-diacrylamidobenzoic acid based hyper-cross-linked resin for the efficient adsorption of Congo Red and Rhodamine B [J].
Waheed, Abdul ;
Mansha, Muhammad ;
Kazi, Izzat Wajih ;
Ullah, Nisar .
JOURNAL OF HAZARDOUS MATERIALS, 2019, 369 :528-538