Synthesis and crystal structure of trinuclear zinc coordination polymer based on a triangle flexible carboxylic ligand

被引：9
|
作者：
Zhang, Ming-Dao [1 ]
Di, Chang-Miao [1 ]
Zheng, He-Gen [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 27卷
关键词：
Trinuclear core; Flexible carboxylic ligand; Coordination polymer; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS;
D O I：
10.1016/j.inoche.2012.10.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Flexible carboxylic ligands have attracted considerable interest due to their excellent stretchable capacity and coordinative ability. In this paper, one new 2D zinc coordination polymer {[Zn(tcpob)(2/3)(H2O)(2/3)]center dot(H2O)(2/3)}(n) with trinuclear zinc cluster units was prepared under hydrothermal conditions based on 1,3,5-tri(4-carboxyphenoxy)benzene ligand. In addition, the solid-state photoluminescent spectra were measured at room temperature. Published by Elsevier B.V.
引用
收藏
页码：88 / 91
页数：4
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