Effective charge collection in dye-sensitized nanocrystalline TiO2

被引:4
作者
Yanagida, Masatoshi [1 ,2 ]
Numata, Youhei [2 ]
Yoshimatsu, Keiichi [2 ]
Satoh, Shin [2 ]
Han, Liyuan [2 ]
机构
[1] Natl Inst Mat Sci, Global Res Ctr Environm & Energy Based Nanomat Sc, Tsukuba, Ibaraki 3050047, Japan
[2] Natl Inst Mat Sci, Photovolta Mat Res Unit, Tsukuba, Ibaraki 3050047, Japan
关键词
dye-sensitized solar cells; nanocrystalline; TiO2; electron transport; charge collection;
D O I
10.1088/2043-6262/4/1/015006
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The effective charge collection in dye-sensitized solar cells (DSCs) is an important factor to improve the efficiency. Here, we report the comparison of three types of structures in DSCs. One type of structure is a sandwich-type DSC (SW-DSC), in which the TiO2 film is sandwiched between a TCO glass front electron-collection electrode and a sputtered Ti back collection electrode. The second is a normal DSC (N-DSC), which has no back electrode. The third is a back-contact-type DSC (BC-DSC), in which a sputtered Ti back electrode is deposited on a TiO2 film on the opposite side of the normal glass as an optical window. The photocurrent response of an SW-DSC is the fastest of the three structures due to using intensity modulated photocurrent spectroscopy, which can be explained by the electron diffusion model. The model shows that the SW-DSC is a favorable structure for effective charge collection in DSCs.
引用
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页数:8
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