Observation of Mode-Specific Vibrational Autodetachment from Dipole-Bound States of Cold Anions

被引：109

作者：

Liu, Hong-Tao ^{[1
]}

Ning, Chuan-Gang ^{[2
]}

Huang, Dao-Ling ^{[1
]}

Dau, Phuong Diem ^{[1
]}

Wang, Lai-Sheng ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

[2] Tsinghua Univ, State Key Lab Low Dimens Quantum Phys, Beijing 100084, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 34期

基金：

美国国家科学基金会;

关键词：

dipole-bound states; electron autodetachment; phenoxides; photoelectron spectroscopy; radicals; PHOTOELECTRON-SPECTROSCOPY; NEGATIVE-IONS; POLAR-MOLECULES; SUPPORTED STATE; GROUND-STATE; ELECTRON; PHOTODETACHMENT; AUTOIONIZATION; DYNAMICS; THIOPHENOXIDE;

D O I：

10.1002/anie.201304695

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dipole-bound states: Electron autodetachment of vibrationally excited dipole-bound states of phenoxide anions is observed by photoelectron spectroscopy. The wave function of a dipole-bound state and the observed normal modes are shown. The blue lobe of the orbital indicates that the electron is weakly bound to the dipole. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8976 / 8979

页数：4

共 37 条

[1] Vibrational Autodetachment-Intramolecular Vibrational Relaxation Translated into Electronic Motion [J].