Selective Hydrogenation of Acetylene and Physicochemical Properties of Pd-Fe/Al2O3 Bimetallic Catalysts

被引：13

作者：

Stytsenko, V. D. ^{[1
]}

Mel'nikov, D. P. ^{[1
]}

Tkachenko, O. P. ^{[2
]}

Savel'eva, E. V. ^{[1
]}

Semenov, A. P. ^{[1
]}

Kustov, L. M. ^{[2
]}

机构：

[1] Gubkin Russian State Univ Oil & Gas, Moscow, Russia

[2] Russian Acad Sci, Zelinskii Inst Organ Chem, Moscow, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2018年 / 92卷 / 05期

基金：

俄罗斯基础研究基金会;

关键词：

selective hydrogenation; acetylene; Pd-Fe/Al2O3; decomposition of ferrocene; ALLOY CATALYSTS; PD; FE; AG;

D O I：

10.1134/S0036024418050308

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The selective hydrogenation of acetylene on Pd-Fe/Al2O3 catalysts prepared by decomposition of ferrocene on reduced Pd/Al2O3 was studied. The effect of the conditions of treatment of the Pd-ferrocene/ Al2O3 precursor on the catalyst activity and selectivity was investigated, and the optimum conditions were determined at which the Pd-Fe/Al2O3 catalyst has higher selectivity than Pd/Al2O3 without any loss of activity.

引用

页码：862 / 869

页数：8

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