Synthesis and structure of a new layered aluminium phosphate: [BuNH3](3)[Al3P4O16]

被引：59

作者：

Chippindale, AM

Cowley, AR

Huo, QS

Jones, RH

Law, AD

Thomas, JM

Xu, RR

机构：

[1] UNIV KEELE, DEPT CHEM, KEELE ST5 5BG, STAFFS, ENGLAND

[2] UCL ROYAL INST GREAT BRITAIN, DAVY FARADAY RES LAB, LONDON W1X 4BS, ENGLAND

[3] JILIN UNIV, DEPT CHEM, CHANGCHUN 130023, PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 15期

关键词：

D O I：

10.1039/a701397c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new two-dimensional aluminium phosphate, [BuNH3](3)[Al3P4O16], has been synthesized under solvothermal conditions at 453 K using butylamine as template. The structure, solved using single-crystal X-ray diffraction data measured at 200 K [trigonal, space group P (3) over bar, a = 13.158(2), c = 9.633(2) Angstrom, U= 1444.4 Angstrom(3), Z = 2], consists of AAAA-stacked [Al3P4O16](3-) layers containing 12-membered rings of alternating AlO4 and PO4 tetrahedra. Disordered butylammonium cations lie between the layers with their hydrophobic tails pointing into the channels bounded by the 12-membered rings.

引用

页码：2639 / 2643

页数：5

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