Nanoporous Titania-Supported Gold Nanoparticle-Catalyzed Green Synthesis of 1,2,3-Triazoles in Aqueous Medium

被引：68
|
作者：
Boominathan, Muthusamy [1 ]
Pugazhenthiran, Nalenthiran [2 ]
Nagaraj, Muthupandi [1 ]
Muthusubramanian, Shanmugam [1 ]
Murugesan, Sepperumal [2 ]
Bhuvanesh, Nattamai [3 ]
机构：
[1] Madurai Kamaraj Univ, Sch Chem, Dept Organ Chem, Madurai 625021, Tamil Nadu, India
[2] Madurai Kamaraj Univ, Sch Chem, Dept Inorgan Chem, Madurai 625021, Tamil Nadu, India
[3] Texas A&M Univ, Dept Chem, Xray Diffract Lab, College Stn, TX 77842 USA
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2013年 / 1卷 / 11期
关键词：
Gold nanoparticles; Cycloaddition; Huisgen reaction; Heterogeneous catalysis; Triazole; SURFACE ORGANOMETALLIC CHEMISTRY; AZIDE-ALKYNE CYCLOADDITION; ONE-POT SYNTHESIS; 1,3-DIPOLAR CYCLOADDITION; DEPOSITION-PRECIPITATION; REGIOSELECTIVE SYNTHESIS; HETEROGENEOUS CATALYSIS; ORGANIC-REACTIONS; TERMINAL ALKYNES; CLICK CHEMISTRY;
D O I：
10.1021/sc400147r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nanoporous titania-supported gold nanoparprecipitation method, and the synthesized nanoparticles have been characterized by XRD, SEM, HRTEM, EDAX, BET adsorption isotherm, and IR and UV vis spectral techniques. The efficiency of this catalyst toward green organic synthesis has been studied by carrying out the 1,3-dipolar cycloaddition of organic azides with a variety of terminal alkynes in water. The reaction proceeds regioselectively yielding the corresponding 1,4-disubstituted-1,2,3-triazole derivative in good to excellent yield.
引用
收藏
页码：1405 / 1411
页数：7
相关论文
共 50 条
  • [41] Recent Progress in the Synthesis of N2-Substituted 1,2,3-Triazoles
    Zhu, Lili
    Zhang, Hui
    Wang, Chunjie
    Chen, Zili
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2018, 38 (05) : 1052 - 1064
  • [42] Synthesis and catalytic activity of carbon supported copper nanoparticles for the synthesis of aryl nitriles and 1,2,3-triazoles
    Nasrollahzadeh, Mahmoud
    Jaleh, Babak
    Fakhri, Parisa
    Zahraei, Ali
    Ghadery, Esmaeil
    RSC ADVANCES, 2015, 5 (04): : 2785 - 2793
  • [43] A practical flow synthesis of 1,2,3-triazoles
    Drelinkiewicz, Dawid
    Whitby, Richard J.
    RSC ADVANCES, 2022, 12 (45) : 28910 - 28915
  • [44] Efficient synthesis of deuterated 1,2,3-triazoles
    Gonda, Zsombor
    Loerincz, Krisztian
    Novak, Zoltan
    TETRAHEDRON LETTERS, 2010, 51 (48) : 6275 - 6277
  • [45] Preparation of alumina supported copper nanoparticles and their application in the synthesis of 1,2,3-triazoles
    Kantam, M. Lakshmi
    Jaya, V. Swarna
    Sreedhar, B.
    Rao, M. Mohan
    Choudary, B. M.
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 256 (1-2) : 273 - 277
  • [46] Recyclable clay supported Cu (II) catalyzed tandem one-pot synthesis of 1-aryl-1,2,3-triazoles
    Mohammed, Shabber
    Padala, Anil K.
    Dar, Bashir A.
    Singh, Baldev
    Sreedhar, B.
    Vishwakarma, Ram A.
    Bharate, Sandip B.
    TETRAHEDRON, 2012, 68 (39) : 8156 - 8162
  • [47] Another Way to the Synthesis of 1,2,3-Triazoles
    Xu, Beihua
    Hu, Yongzhou
    JOURNAL OF HETEROCYCLIC CHEMISTRY, 2013, 50 (05) : 1217 - 1222
  • [48] Hydrothermally Developed ZnC2O4.2H2O Nanocrystals as Efficient Copper-free Catalyst for the Synthesis of 1,4-Disubstituted 1,2,3-Triazoles in Water
    Gogoi, Priyanka
    Bhattacharyya, Bishal
    Chakravorty, Vishal
    Garg, Anirban
    Hazarika, Priyanuj Krishnann
    Deori, Kalyanjyoti
    Sarma, Diganta
    CHEMNANOMAT, 2023, 9 (02)
  • [49] Regiospecific Aza-Michael Addition of 4-Aryl-1H-1,2,3-triazoles to Chalcones: Synthesis of 2,4-Disubstituted 1,2,3-Triazoles in Basic Medium
    Bhagat, Ujjawal Kumar
    Peddinti, Rama Krishna
    SYNLETT, 2018, 29 (01) : 99 - 105
  • [50] Synthesis, characterization and crystal structure of a diketone based Cu(II) complex and its catalytic activity for the synthesis of 1,2,3-triazoles
    Layek, Samaresh
    Kumari, Shweta
    Anuradha
    Agrahari, Bhumika
    Ganguly, Rakesh
    Pathak, Devendra D.
    INORGANICA CHIMICA ACTA, 2016, 453 : 735 - 741
12345