Nanoporous Titania-Supported Gold Nanoparticle-Catalyzed Green Synthesis of 1,2,3-Triazoles in Aqueous Medium

被引：68
|
作者：
Boominathan, Muthusamy [1 ]
Pugazhenthiran, Nalenthiran [2 ]
Nagaraj, Muthupandi [1 ]
Muthusubramanian, Shanmugam [1 ]
Murugesan, Sepperumal [2 ]
Bhuvanesh, Nattamai [3 ]
机构：
[1] Madurai Kamaraj Univ, Sch Chem, Dept Organ Chem, Madurai 625021, Tamil Nadu, India
[2] Madurai Kamaraj Univ, Sch Chem, Dept Inorgan Chem, Madurai 625021, Tamil Nadu, India
[3] Texas A&M Univ, Dept Chem, Xray Diffract Lab, College Stn, TX 77842 USA
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2013年 / 1卷 / 11期
关键词：
Gold nanoparticles; Cycloaddition; Huisgen reaction; Heterogeneous catalysis; Triazole; SURFACE ORGANOMETALLIC CHEMISTRY; AZIDE-ALKYNE CYCLOADDITION; ONE-POT SYNTHESIS; 1,3-DIPOLAR CYCLOADDITION; DEPOSITION-PRECIPITATION; REGIOSELECTIVE SYNTHESIS; HETEROGENEOUS CATALYSIS; ORGANIC-REACTIONS; TERMINAL ALKYNES; CLICK CHEMISTRY;
D O I：
10.1021/sc400147r
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Nanoporous titania-supported gold nanoparprecipitation method, and the synthesized nanoparticles have been characterized by XRD, SEM, HRTEM, EDAX, BET adsorption isotherm, and IR and UV vis spectral techniques. The efficiency of this catalyst toward green organic synthesis has been studied by carrying out the 1,3-dipolar cycloaddition of organic azides with a variety of terminal alkynes in water. The reaction proceeds regioselectively yielding the corresponding 1,4-disubstituted-1,2,3-triazole derivative in good to excellent yield.
引用
收藏
页码：1405 / 1411
页数：7
相关论文
共 50 条
  • [31] CuO-Nanoparticles Catalyzed Synthesis of 1,4-Disubstituted-1,2,3-Triazoles from Bromoalkenes
    Raj, John Paul
    Gangaprasad, Dasari
    Vajjiravel, Murugesan
    Karthikeyan, Kesavan
    Elangovan, Jebamalai
    JOURNAL OF CHEMICAL SCIENCES, 2018, 130 (05)
  • [32] Efficient Synthesis of 1-Sulfonyl-1,2,3-triazoles
    Raushel, Jessica
    Fokin, Valery V.
    ORGANIC LETTERS, 2010, 12 (21) : 4952 - 4955
  • [33] The Use of Copper Flow Reactor Technology for the Continuous Synthesis of 1,4-Disubstituted 1,2,3-Triazoles
    Bogdan, Andrew R.
    Sach, Neal W.
    ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (06) : 849 - 854
  • [34] Tandem synthesis of 1-formyl-1,2,3-triazoles
    Fletcher, James T.
    Christensen, Joseph A.
    Villa, Eric M.
    TETRAHEDRON LETTERS, 2017, 58 (47) : 4450 - 4454
  • [35] Microwave accelerated green approach for tailored 1,2,3-triazoles via CuAAC
    George, Nancy
    Singh, Gurleen
    Singh, Riddima
    Singh, Gurjaspreet
    Devi, Anita
    Singh, Harminder
    Kaur, Gurpreet
    Singh, Jandeep
    SUSTAINABLE CHEMISTRY AND PHARMACY, 2022, 30
  • [36] Efficient, mild synthesis of N-unsubstituted 1,2,3-triazoles from methanolysis of 1-sulfonyl-1,2,3-triazoles
    Rodriguez-Florencio, Janeth
    Martinez-Otero, Diego
    Garcia-Eleno, Marco A.
    Cuevas-Yanez, Erick
    SYNTHETIC COMMUNICATIONS, 2018, 48 (17) : 2189 - 2197
  • [37] Organocatalytic Selective [3+2] Cycloadditions: Synthesis of Functionalized 5-Arylthiomethy1-1,2,3-triazoles and 4-Arylthio-1,2,3-triazoles
    Reddy, G. Surendra
    Reddy, L. Mallikarjuna
    Kumar, A. Suresh
    Ramachary, Dhevalapally B.
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (23): : 15488 - 15501
  • [38] Green synthesis and anticancer potential of chalcone linked-1,2,3-triazoles
    Yadav, Pinki
    Lal, Kashmiri
    Kumar, Ashwani
    Guru, Santosh Kumar
    Jaglan, Sundeep
    Bhushan, Shashi
    EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2017, 126 : 944 - 953
  • [39] Synthesis and applications of fluorinated, polyfluoroalkyl- and polyfluoroaryl-substituted 1,2,3-triazoles
    Bugden, Frances E.
    Westwood, Jason L.
    Stone, Henry
    Xu, Yingjian
    Greenhalgh, Mark
    ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (20): : 5938 - 5984
  • [40] General Solution to the Synthesis of N-2-Substituted 1,2,3-Triazoles
    Wang, Xiao-Jun
    Zhang, Li
    Krishnamurthy, Dhileepkumar
    Senanayake, Chris H.
    Wipf, Peter
    ORGANIC LETTERS, 2010, 12 (20) : 4632 - 4635
12345