Nanoporous Titania-Supported Gold Nanoparticle-Catalyzed Green Synthesis of 1,2,3-Triazoles in Aqueous Medium

被引：68

作者：

Boominathan, Muthusamy ^{[1
]}

Pugazhenthiran, Nalenthiran ^{[2
]}

Nagaraj, Muthupandi ^{[1
]}

Muthusubramanian, Shanmugam ^{[1
]}

Murugesan, Sepperumal ^{[2
]}

Bhuvanesh, Nattamai ^{[3
]}

机构：

[1] Madurai Kamaraj Univ, Sch Chem, Dept Organ Chem, Madurai 625021, Tamil Nadu, India

[2] Madurai Kamaraj Univ, Sch Chem, Dept Inorgan Chem, Madurai 625021, Tamil Nadu, India

[3] Texas A&M Univ, Dept Chem, Xray Diffract Lab, College Stn, TX 77842 USA

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2013年 / 1卷 / 11期

关键词：

Gold nanoparticles; Cycloaddition; Huisgen reaction; Heterogeneous catalysis; Triazole; SURFACE ORGANOMETALLIC CHEMISTRY; AZIDE-ALKYNE CYCLOADDITION; ONE-POT SYNTHESIS; 1,3-DIPOLAR CYCLOADDITION; DEPOSITION-PRECIPITATION; REGIOSELECTIVE SYNTHESIS; HETEROGENEOUS CATALYSIS; ORGANIC-REACTIONS; TERMINAL ALKYNES; CLICK CHEMISTRY;

D O I：

10.1021/sc400147r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous titania-supported gold nanoparprecipitation method, and the synthesized nanoparticles have been characterized by XRD, SEM, HRTEM, EDAX, BET adsorption isotherm, and IR and UV vis spectral techniques. The efficiency of this catalyst toward green organic synthesis has been studied by carrying out the 1,3-dipolar cycloaddition of organic azides with a variety of terminal alkynes in water. The reaction proceeds regioselectively yielding the corresponding 1,4-disubstituted-1,2,3-triazole derivative in good to excellent yield.

引用

页码：1405 / 1411

页数：7

共 50 条

[21] Green synthesis of 1-monosubstituted 1,2,3-triazoles via 'click chemistry' in water
Wu, Luyong
Yan, Bo
Yang, Guo
Chen, Yuxue
HETEROCYCLIC COMMUNICATIONS, 2013, 19 (06) : 397 - 400
[22] CuO-NiO bimetallic nanoparticles supported on graphitic carbon nitride with enhanced catalytic performance for the synthesis of 1,2,3-triazoles, bis-1,2,3-triazoles, and tetrazoles in parts per million level
Gajurel, Sushmita
Dam, Binoyargha
Bhushan, Mayank
Singh, L. Robindro
Pal, Amarta Kumar
APPLIED ORGANOMETALLIC CHEMISTRY, 2022, 36 (02)
[23] Controlled Synthesis of Different Morphologies of Cu-MgO and Their Application as Catalysts in Synthesis of 1,2,3-Triazoles Following Different Pathways
Roy, Biplab
Panda, Asit B.
Chattopadhyay, Asoke P.
CHEMISTRYSELECT, 2017, 2 (24): : 7340 - 7352
[24] Copper-catalyzed decarboxylative regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles
Kumar, Navaneet
Ansari, Mohd Yeshab
Kant, Ruchir
Kumar, Atul
CHEMICAL COMMUNICATIONS, 2018, 54 (21) : 2627 - 2630
[25] Sulfur-Containing 1,2,3-Triazoles: Synthesis and Properties
Peng, Lifen
Chen, Jiayi
Chen, Yi
Lu, Hao
Okuda, Yasuhiro
Tang, Zilong
Orita, Akihiro
Qiu, Renhua
Yin, Shuang-Feng
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2024, 27 (06)
[26] Aqueous bile salt accelerated cascade synthesis of 1,2,3-triazoles from arylboronic acids
Garg, Anirban
Ali, Abdul Aziz
Damarla, Krishnaiah
Kumar, Arvind
Sarma, Diganta
TETRAHEDRON LETTERS, 2018, 59 (45) : 4031 - 4035
[27] Green synthesis of 1,4-disubstituted 1,2,3-triazoles: a sustainable approach
Kumar, Sachin
Lal, Bajrang
Tittal, Ram Kumar
GREEN CHEMISTRY, 2024, 26 (04) : 1725 - 1769
[28] Recent Catalysts Used in the Synthesis of 1,4-Disubstituted 1,2,3-Triazoles by Heterogeneous and Homogeneous Methods
Noriega, Saul
Leyva, Elisa
Moctezuma, Edgar
Flores, Luisa
Loredo-Carrillo, Silvia
CURRENT ORGANIC CHEMISTRY, 2020, 24 (05) : 536 - 549
[29] Palladium-Catalyzed C-H Arylation of 1,2,3-Triazoles
Zhang, Chengwei
You, Lin
Chen, Chuo
MOLECULES, 2016, 21 (10)
[30] Silver-catalyzed three-component reaction: synthesis of N2-substituted 1,2,3-triazoles via direct benzylic amination
Liu, Zhenhua
Hao, Wenjing
Gao, Wen
Zhu, Guangyu
Li, Xiang
Tong, Lili
Tang, Bo
SCIENCE CHINA-CHEMISTRY, 2019, 62 (08) : 1001 - 1006

← 1 2 3 4 5 →