Selective Oxidation of Organic Substrates in Presence of H2O2 using a Polymer-Anchored Iron(III)-Ferrocene Complex

被引：16

作者：

Islam, S. K. Manirul ^{[1
]}

Paul, Sumantra ^{[1
]}

Roy, Anupam Singha ^{[1
]}

Mondal, Paramita ^{[1
]}

机构：

[1] Univ Kalyani, Dept Chem, Nadia 741235, W Bengal, India

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2013年 / 23卷 / 03期

关键词：

Alkane oxidation; Alcohol oxidation; Polymer anchored; Iron Schiff base catalyst; Hydrogen peroxide; C-H OXIDATION; COPPER(II) COMPLEXES; CATALYTIC-OXIDATION; ALKANES; IRON; CYCLOHEXENE; EPOXIDATION; ALDEHYDES; ALCOHOLS; OLEFINS;

D O I：

10.1007/s10904-012-9813-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An eco-friendly, cheap and reusable polymer-anchored iron(III)-ferrocene Schiff base catalyst has been designed for the efficient oxidation of alkanes and alcohols. Oxidation reactions were done by using a greener oxidant 30 % aqueous hydrogen peroxide in acetonitrile medium at room temperature for alcohols and at 60 A degrees C for alkanes. Both the alkanes and alcohols have been selectively oxidized to their corresponding aldehydes and ketones in excellent yields. This catalyst has shown excellent catalytic activity with high selectivity and recyclability. It is found that this catalyst can be reused up to six cycles without loss of its original activities.

引用

页码：560 / 570

页数：11

共 50 条

[21] Hydrocarbon oxidation by homogeneous and heterogeneous non-heme iron (III) catalysts with H2O2
Bilis, G.
Christoforidis, K. C.
Deligiannakis, Y.
Louloudi, M.
CATALYSIS TODAY, 2010, 157 (1-4) : 101 - 106
[22] Highly Efficient Aromatic C-H Oxidation with H2O2 in the Presence of Iron Complexes of the PDP Family
Tkachenko, Nikolay V.
Ottenbacher, Roman V.
Lyakin, Oleg Y.
Zima, Alexandra M.
Samsonenko, Denis G.
Talsi, Evgenii P.
Bryliakov, Konstantin P.
CHEMCATCHEM, 2018, 10 (18) : 4052 - 4057
[23] Alcohol oxidation with H2O2 catalyzed by a cheap and promptly available imine based iron complex
Olivo, Giorgio
Giosia, Simone
Barbieri, Alessia
Lanzalunga, Osvaldo
Di Stefano, Stefano
ORGANIC & BIOMOLECULAR CHEMISTRY, 2016, 14 (45) : 10630 - 10635
[24] Selective oxidation of cyclopentene with H2O2 by using H3PW12O40 and TBAB as a phase transfer catalyst
Luo, Yaling
Liu, Changjun
Yue, Hairong
Tang, Siyang
Zhu, Yingming
Liang, Bin
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2019, 27 (08) : 1851 - 1856
[25] Selective Oxidation of Sulfides to Sulfones Using H2O2 and Anderson-Type Hexamolybdochromate(III) as Catalyst
Supale, Amit R.
Gokavi, Gavisiddappa S.
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (04) : 725 - 731
[26] Asymmetric Epoxidation of Olefins with H2O2 Catalyzed by a Bioinspired Aminopyridine N4 Iron Complex
Wang, Wenfang
Sun, Qiangsheng
Xu, Daqian
Xia, Chungu
Sun, Wei
CHEMCATCHEM, 2017, 9 (03) : 420 - 424
[27] As(III) removal by Fe(III)-amidoximated PAN in the presence of H2O2 through simultaneous oxidation and adsorption
Gao, Luyao
Hao, Mengna
Bu, Fanling
Ji, Chunnuan
Qu, Rongjun
Sun, Changmei
Zhang, Ying
WATER SUPPLY, 2020, 20 (02) : 565 - 573
[28] Selective Oxidation of Activated Alcohols by the Combination of H2O2, AcOH and NaBr: An Efficient Metal-Free Alternative
Qi, Xingyi
Wang, Jing
Zheng, Liwei
Qi, Lin
SYNLETT, 2011, (04) : 555 - 558
[29] VO2F(dmpz)2: a new catalyst for selective oxidation of organic sulfides to sulfoxides with H2O2
Hussain, Sahid
Talukdar, Dhrubajyoti
Bharadwaj, Saitanya K.
Chaudhuri, Mihir K.
TETRAHEDRON LETTERS, 2012, 53 (48) : 6512 - 6515
[30] Monochloramine Formation and Decay in the Presence of H2O2 after UV/H2O2 Advanced Oxidation
Wang, Chengjin
Zheng, Liang
Andrews, Susan
Hofmann, Ron
JOURNAL OF ENVIRONMENTAL ENGINEERING, 2020, 146 (06)

← 1 2 3 4 5 →