Selective Oxidation of Organic Substrates in Presence of H2O2 using a Polymer-Anchored Iron(III)-Ferrocene Complex

被引：16

作者：

Islam, S. K. Manirul ^{[1
]}

Paul, Sumantra ^{[1
]}

Roy, Anupam Singha ^{[1
]}

Mondal, Paramita ^{[1
]}

机构：

[1] Univ Kalyani, Dept Chem, Nadia 741235, W Bengal, India

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2013年 / 23卷 / 03期

关键词：

Alkane oxidation; Alcohol oxidation; Polymer anchored; Iron Schiff base catalyst; Hydrogen peroxide; C-H OXIDATION; COPPER(II) COMPLEXES; CATALYTIC-OXIDATION; ALKANES; IRON; CYCLOHEXENE; EPOXIDATION; ALDEHYDES; ALCOHOLS; OLEFINS;

D O I：

10.1007/s10904-012-9813-6

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

An eco-friendly, cheap and reusable polymer-anchored iron(III)-ferrocene Schiff base catalyst has been designed for the efficient oxidation of alkanes and alcohols. Oxidation reactions were done by using a greener oxidant 30 % aqueous hydrogen peroxide in acetonitrile medium at room temperature for alcohols and at 60 A degrees C for alkanes. Both the alkanes and alcohols have been selectively oxidized to their corresponding aldehydes and ketones in excellent yields. This catalyst has shown excellent catalytic activity with high selectivity and recyclability. It is found that this catalyst can be reused up to six cycles without loss of its original activities.

引用

页码：560 / 570

页数：11

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