Preparation of zirconium carbonate as water-tolerant solid base catalyst for glucose isomerization and one-pot synthesis of levulinic acid with solid acid catalyst

被引:38
作者
Pham Anh Son [1 ]
Nishimura, Shun [1 ]
Ebitani, Kohki [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan
关键词
Glucose; Fructose; Isomerization; Zirconium carbonate; Levulinic acid; EXCHANGE RESIN ALUMINATE; D-FRUCTOSE; INDUSTRIALLY-IMPORTANT; GAMMA-VALEROLACTONE; CONVERSION; BIOMASS; CHEMICALS; ION; DEHYDRATION; COMPLEXES;
D O I
10.1007/s11144-013-0642-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this research, zirconium compounds were prepared as water-tolerant solid base catalysts by a simple method. Their catalytic activities were investigated in the aqueous glucose-fructose isomerization reaction. The zirconium carbonate (ZrC) catalyst could work in wide range of reaction temperature (80-140 A degrees C) and the maximum glucose conversion reached 45 % at 120 A degrees C with 76 % selectivity to fructose. The ZrC catalyst was found to retain its activity without significant decrease in the fructose yield after being used for five times. In the one-pot transformation of glucose to levulinic acid (LA), the ZrC could afford 17 % yield of LA after 12 h reaction in water-toluene biphasic solvents in combination with a solid acid catalyst, Amberlyst-15. The proposed reaction system in water-toluene biphasic solvents occurred faster and gave higher LA yield than that in pure water solvent.
引用
收藏
页码:183 / 197
页数:15
相关论文
共 50 条
[31]   Efficient hydrolysis of cellulose to glucose in water by agricultural residue-derived solid acid catalyst [J].
Su, Jialei ;
Qiu, Mo ;
Shen, Feng ;
Qi, Xinhua .
CELLULOSE, 2018, 25 (01) :17-22
[32]   One-step Preparation of Kraft Lignin Derived Mesoporous Carbon as Solid Acid Catalyst for Fructose Conversion to 5-Hydroxymethylfurfural [J].
Li, Xianfa ;
Li, Peiyuan ;
Ding, Daojun ;
Chen, Ke ;
Zhang, Lin ;
Xie, Yu .
BIORESOURCES, 2018, 13 (02) :4428-4439
[33]   One-Pot Synthesis of 5-Hydroxymethylfurfural from Glucose by Bronsted Acid-Free Bifunctional Porous Coordination Polymers in Water [J].
Liang, Fengbing ;
Chen, Dawei ;
Liu, Huizhou ;
Liu, Weimin ;
Xian, Mo ;
Feng, Dexin .
ACS OMEGA, 2019, 4 (05) :9316-9323
[34]   Base free, one-pot synthesis of lactic acid from glycerol using a bifunctional Pt/Sn-MFI catalyst [J].
Cho, Hong Je ;
Chang, Chun-Chih ;
Fan, Wei .
GREEN CHEMISTRY, 2014, 16 (07) :3428-3433
[35]   Titanium Phosphate Grafted on Mesoporous SBA-15 Silica as a Solid Acid Catalyst for the Synthesis of 5-Hydroxymethylfurfural from Glucose [J].
Guo, Wenze ;
Hensen, Emiel J. M. ;
Qi, Wei ;
Heeres, Hero J. ;
Yue, Jun .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2022, 10 (31) :10157-10168
[36]   Cs salt of tungstophosphoric acid-promoted zirconium titanium phosphate solid acid catalyst: An active catalyst for the synthesis of bisphenols [J].
Biswal, Niranjan ;
Das, Dipti Prakasini ;
Parida, Kulamani .
JOURNAL OF CHEMICAL SCIENCES, 2014, 126 (02) :455-465
[37]   One-pot synthesized multi-functional graphene oxide as a water-tolerant and efficient metal-free heterogeneous catalyst for cycloaddition reaction [J].
Lan, Dong-Hui ;
Chen, Lang ;
Au, Chak-Tong ;
Yin, Shuang-Feng .
CARBON, 2015, 93 :22-31
[38]   One-Pot Synthesis of Carbon-Based Solid Acid Polymer Catalyst: Efficient Catalysts for Liquid-Phase Nitration of Alkanes [J].
Wang, Hefang ;
Li, Xuehan ;
Wang, Yuanyuan ;
Yang, Yongfang ;
Jia, Liyuan ;
Wang, Yanji .
CHEMISTRYSELECT, 2020, 5 (22) :6652-6657
[39]   One-pot efficient conversion of glucose into biofuel 5-ethoxymethylfurfural catalyzed by zeolite solid catalyst [J].
Zhangbin Zheng ;
Chen Wang ;
Yihang Chen ;
Shijie Wang ;
Qianhui Guo ;
Chun Chang ;
Hongge Tao ;
Guizhuan Xu .
Biomass Conversion and Biorefinery, 2023, 13 :8927-8938
[40]   Solid acid catalyst prepared via one-step microwave-assisted hydrothermal carbonization: Enhanced stability towards intensified production of 5-hydroxymethylfurfural in water/γ-valerolactone/NaCl [J].
Siabbamrung, Phornwimol ;
Quitain, Armando T. ;
Kida, Tetsuya ;
Laosiripojana, Navadol ;
Boonnoun, Panatpong ;
Shotipruk, Artiwan .
MOLECULAR CATALYSIS, 2021, 512 (512)