Modulation of the copper-dioxygen reactivity by stereochemical effect of tetradentate tripodal ligands

被引：30

作者：

Hayashi, H

Uozumi, K

Fujinami, S

Nagatomo, S

Shiren, K

Furutachi, H

Suzuki, M

Uehara, A

Kitagawa, T

机构：

[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan

[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 03期

关键词：

D O I：

10.1246/cl.2002.416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dioxygen reactivity of a copper(I) complex having a sterically hindered Me-3-tpa and monooxygenase activity of its oxygenated species toward the ligand were significantly modulated by the presence of the 6-methyl group onto pyridyl group.

引用

页码：416 / 417

页数：2

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