Pore Sealing of Porous Ultralow-k Dielectrics by Self-Assembled Monolayers Combined with Atomic Layer Deposition

被引:22
作者
Armini, S. [1 ]
Prado, J. Loyo [1 ]
Swerts, J. [1 ]
Sun, Y. [1 ]
Krishtab, M. [1 ]
Meersschaut, J. [1 ]
Blauw, M. [2 ]
Baklanov, M. [1 ]
Verdonck, P. [1 ]
机构
[1] IMEC, B-3001 Louvain, Belgium
[2] Holst Ctr, Eindhoven, Netherlands
关键词
PLASMA; DAMAGE;
D O I
10.1149/2.012202ssl
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Due to its excellent step coverage characteristics, atomic layer depositions (ALD) deposit their material not only on top of underlying surfaces but also into the pores of porous low-k films. In this study, the film characteristics caused by pre-treatments of the low-k material, followed by deposition of self assembled monolayers (SAMs) from an 11-cyanoundecyltrichlorosilane precursor and finally by an HfO2 Atomic Layer Deposition were determined. By adequate optimization of the surface treatment, the SAM deposition and the ALD it was possible to obtain complete pore sealing after ALD, without penetration of the Hf into de porous low-k film. (C) 2012 The Electrochemical Society. [DOI: 10.1149/2.012202ssl] All rights reserved.
引用
收藏
页码:P42 / P44
页数:3
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